Poly(9,9-dialkyl-3,6-dibenzosilole) - a high energy gap host for phosphorescent light emitting devices

被引：93
作者：
Chan, KL
Watkins, SE
Mak, CSK
McKiernan, MJ
Towns, CR
Pascu, SI
Holmes, AB
机构：
[1] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Cambridge CB2 1EW, England
[2] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia
[3] Univ Melbourne, Bio21 Inst, Parkville, Vic 3010, Australia
[4] Cambridge Display Technol Ltd, Cambridge CB3 6DW, England
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 46期
关键词：
D O I：
10.1039/b511208g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The preparation of the 3,6-disubstituted dibenzosilole monomers 4, 5 and 10 by two different routes is described; Suzuki opolymerisation afforded poly(9,9-dioctyl-3,6-dibenzosilole) 11 which has a sufficiently high triplet energy (2.55 eV) to function as a host for green electrophosphorescent emitters.
引用
收藏
页码：5766 / 5768
页数：3
相关论文
共 35 条
[21]   1,8-naphthalimides in phosphorescent organic LEDs: The interplay between dopant, exciplex, and host emission [J].
Kolosov, D ;
Adamovich, V ;
Djurovich, P ;
Thompson, ME ;
Adachi, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (33) :9945-9954
[22]  
KRAFT A, 1998, ANGEW CHEM, V113, P416
[23]   Cyclometalated Ir complexes in polymer organic light-emitting devices [J].
Lamansky, S ;
Djurovich, PI ;
Abdel-Razzaq, F ;
Garon, S ;
Murphy, DL ;
Thompson, ME .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (03) :1570-1575
[24]   Tuning of emission color for blue dendrimer blend light-emitting diodes [J].
Markham, JPJ ;
Namdas, EB ;
Anthopoulos, TD ;
Samuel, IDW ;
Richards, GJ ;
Burn, PL .
APPLIED PHYSICS LETTERS, 2004, 85 (09) :1463-1465
[25]   Ultraviolet-emitting conjugated polymer poly(9,9′-alkyl-3,6-silafluorene) with a wide band gap of 4.0 eV [J].
Mo, YQ ;
Tian, RY ;
Shi, W ;
Cao, Y .
CHEMICAL COMMUNICATIONS, 2005, (39) :4925-4926
[26]   Highly efficient molecular organic light-emitting diodes based on exciplex emission [J].
Palilis, LC ;
Mäkinen, AJ ;
Uchida, M ;
Kafafi, ZH .
APPLIED PHYSICS LETTERS, 2003, 82 (14) :2209-2211
[27]   Solution-processible conjugated electrophosphorescent polymers [J].
Sandee, AJ ;
Williams, CK ;
Evans, NR ;
Davies, JE ;
Boothby, CE ;
Köhler, A ;
Friend, RH ;
Holmes, AB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (22) :7041-7048
[28]  
Scherf U, 2002, ADV MATER, V14, P477, DOI 10.1002/1521-4095(20020404)14:7<477::AID-ADMA477>3.3.CO
[29]  
2-0
[30]   Carbazole compounds as host materials for triplet emitters in organic light-emitting diodes:: Polymer hosts for high-efficiency light-emitting diodes [J].
van Dijken, A ;
Bastiaansen, JJAM ;
Kiggen, NMM ;
Langeveld, BMW ;
Rothe, C ;
Monkman, A ;
Bach, I ;
Stössel, P ;
Brunner, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (24) :7718-7727
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