Electrochemical trifluoromethylation of dimethyl acetylenedicarboxylate

被引：5
作者：
Dmowski, W
Biernacki, A
机构：
[1] Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warsaw
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 78卷 / 02期
关键词：
electrochemical trifluoromethylation; dimethyl acetylenedicarboxylate; trifluoroacetic acid; trifluoromethylmaleates; trifluoromethylsuccinate; NMR spectroscopy;
D O I：
10.1016/0022-1139(96)03443-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Electrooxidation of trifluoroacetic acid in the presence of dimethyl acetylenedicarboxylate in an acetonitrile/water solution provided cis and trans dimethyl 2,3-bis(trifluoromethyl) maleates and dimethyl 2,2,3-tris (trifluoromethyl) succinate as the main products.
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收藏
页码：193 / 194
页数：2
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