Thermo-electrical instabilities arising in proton exchange membrane of fuel cell

被引:4
作者
Bograchev, D. A. [2 ]
Martemianov, S. [1 ]
机构
[1] Univ Poitiers, Dept Fluides, Branche Fluides, ESIP,ENSMA,CNRS,Inst Pprimme UPR,CNRS 3346, F-86022 Poitiers, France
[2] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia
关键词
Fuel cell; Heat management; Proton exchange membrane; Stability; PLASTIC-DEFORMATION; DURABILITY; PERFORMANCE; STRESSES; MODEL; HEAT; MASS; MEA;
D O I
10.1016/j.ijheatmasstransfer.2011.02.046
中图分类号
O414.1 [热力学];
学科分类号
摘要
A thermo-electrical model of fuel cell proton exchange membrane is developed and the stability of the system is studied. The marginal curves have been obtained as a function of governed dimensionless parameters. The determined dimensionless parameters allow analyzing different scenarios of non-controlled membrane heating. It has been shown that a positive thermo-electrical feedback can cause instability development and membrane damage in real systems. Recommendations for the improvement of heat management in fuel cells have been proposed using the provided stability study. In particular, it has been demonstrated that decreasing of gas diffusion layer thickness has positive effect and stabilizes the system. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3024 / 3030
页数:7
相关论文
共 23 条
  • [1] Stress and plastic deformation of MEA in fuel cells - Stresses generated during cell assembly
    Bograchev, Danfil
    Gueguen, Mikael
    Grandidier, Jean-Claude
    Martemianov, Serguei
    [J]. JOURNAL OF POWER SOURCES, 2008, 180 (01) : 393 - 401
  • [2] Stress and plastic deformation of MEA in running fuel cell
    Bograchev, Daniil
    Gueguen, Mikael
    Grandidier, Jean-Claude
    Martemianov, Serquei
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (20) : 5703 - 5717
  • [3] WATER AND THERMAL MANAGEMENT IN SOLID-POLYMER-ELECTROLYTE FUEL-CELLS
    FULLER, TF
    NEWMAN, J
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (05) : 1218 - 1225
  • [4] HINDS LG, 2004, PERFORMANCE DURABILI
  • [5] A single-phase, non-isothermal model for PEM fuel cells
    Ju, H
    Meng, H
    Wang, CY
    [J]. INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2005, 48 (07) : 1303 - 1315
  • [6] Improvement of proton exchange membrane fuel cell electrical performance by optimization of operating parameters and electrodes preparation
    Kadjo, A. J. J.
    Brault, P.
    Caillard, A.
    Coutanceau, C.
    Gamier, J. -P.
    Martemianov, S.
    [J]. JOURNAL OF POWER SOURCES, 2007, 172 (02) : 613 - 622
  • [7] Performance and instabilities of proton exchange membrane fuel cells
    Kadjo, J. -J. A.
    Garnier, J. -P.
    Maye, J. -P.
    Relot, F.
    Martemianov, S.
    [J]. RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2006, 42 (05) : 467 - 475
  • [8] Direct measurement of through-plane thermal conductivity and contact resistance in fuel cell materials
    Khandelwal, Manish
    Mench, M. M.
    [J]. JOURNAL OF POWER SOURCES, 2006, 161 (02) : 1106 - 1115
  • [9] Analysis of thermal stability of direct methanol fuel cell stack operation
    Kulikovsky, A. A.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (05) : B509 - B516
  • [10] Morphological features (defects) in fuel cell membrane electrode assemblies
    Kundu, S.
    Fowler, M. W.
    Simon, L. C.
    Grot, S.
    [J]. JOURNAL OF POWER SOURCES, 2006, 157 (02) : 650 - 656