Hydrothermal Synthesis and Electrochemical Properties of Complex Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN2)picolinato-κ2N,O] iron(II) tetrahydrate

被引：0

作者：

Zhuang, Ji-Chang ^{[1
]}

Hu, Fei-Long ^{[2
]}

Yin, Xian-Hong ^{[1
]}

Wu, Qiao-Lan ^{[1
]}

Luo, Zhi-Rong ^{[1
]}

Zhuang, Yue ^{[1
]}

机构：

[1] Guangxi Univ Nationalities, Coll Chem & Ecol Engn, Nanning 530006, Peoples R China

[2] ZhongShan Tech Inst, Food & Chem Dept, Zhongshan 528400, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Iron(II) complex; Spectroscopy property; Electrochemical property; COORDINATION CHEMISTRY; ANION; LIGANDS; CLUSTER;

D O I：

10.1007/s10870-010-9976-3

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex has been synthesized by 6-(3,5-dimethyl-1H-pyrazol-1-yl) picolinic acid (DPPA) in the mixed solvent of water and methanol. It crystallizes in the triclinic system, space group P-1 with a = 0.98383 (14), b = 1.08094 (18), c = 1.2774 (2) nm, alpha = 71.0260 (10), beta = 74.5130 (10), gamma = 84.350 (2)degrees, C22H28FeN6O8, M-r = 560.35, V = 1.2379 (3) nm(3), D-c = 1.503 g/cm(3), Z = 2, F(000) = 584, mu(MoK alpha) = 0.669 mm(-1), R = 0.0814 and wR = 0.1624. Structural analysis shows that the iron atom is coordinated with two oxygen atoms from the carboxyl group of the ligand together with four nitrogen atoms from the pyridine rings and pyrazole rings. The spectroscopy and electrochemical properties of the complex has also been described.

引用

页码：787 / 790

页数：4

共 24 条

[1] A well-resolved ice-like (H2O)8 cluster in an organic supramolecular complex [J].

Atwood, JL ;

Barbour, LJ ;

Ness, TJ ;

Raston, CL ;

Raston, PL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (29) :7192-7193

[2] Hexaamminecobalt(III) complexes as multiple hydrogen bond donors:: Synthesis, characterization and X-ray structural study of mixed anion complexes [Co(NH3)6]Br2(BF4) and [Co(NH3)6]Cl2(HC2O4)•H2O [J].

Bala, Ritu ;

Sharma, Raj Pal ;

Sharma, Upendra ;

Burrows, Andrew D. ;

Cassar, Kevin .

JOURNAL OF MOLECULAR STRUCTURE, 2007, 832 (1-3) :156-163

[3] Second-sphere coordination in hexaamminecobalt(III) salt with organic sulphonate anion:: Synthesis, characterisation and X-ray crystal structure of [Co(NH3)6](CH3SO3)3 [J].

Bala, Ritu ;

Sharma, Raj Pal ;

Bond, Andrew D. .

JOURNAL OF MOLECULAR STRUCTURE, 2007, 830 (1-3) :198-203

[4] An intermolecular (H2O)10 cluster in a solid-state supramolecular complex [J].

Barbour, LJ ;

Orr, GW ;

Atwood, JL .

NATURE, 1998, 393 (6686) :671-673

[5] Estimation of individual binding energies in some dimers involving multiple hydrogen bonds using topological properties of electron charge density [J].

Ebrahimi, A. ;

Khorassani, S. M. Habibi ;

Delarami, H. .

CHEMICAL PHYSICS, 2009, 365 (1-2) :18-23

[6] An iron (II) complex containing well-resolved 1D water chain and 1D chain of copper (II) complex with bis(tetrazoly)amine: Syntheses, crystal structures and properties [J].

Guan, Yang-Fan ;

Zhou, Ai-Ju ;

Wang, Dong-Yao ;

Wang, Jing ;

Dong, Wen .

JOURNAL OF MOLECULAR STRUCTURE, 2009, 938 (1-3) :150-155

[7] Five-coordinate anion-bound copper(II) complexes with non-planar tridentate ligands.: X-ray structures of [Cu(L3)(N3)2] and [Cu(L3)(ONO)(OClO3)] (L3=2,6-bis(3,5-dimethyl-pyrazol-1-ylmethyl)pyridine) [J].

Gupta, R ;

Mukherjee, R .

POLYHEDRON, 2001, 20 (19) :2545-2549

[8]

Jones CJ, 1998, CHEM SOC REV, V27, P289

[9]

KHALED RA, 2008, POLYHEDRON, V16, P6528

[10] Formation of two-dimensional supramolecular icelike layer containing (H2O)12 rings [J].

Ma, BQ ;

Sun, HL ;

Gao, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (11) :1374-1376

← 1 2 3 →