Synthesis and Characterization of Cationic Low-Valent Gallium Complexes of Cryptand[2.2.2]

被引：20

作者：

Bourque, Jeremy L. ^{[1
]}

Boyle, Paul D. ^{[1
]}

Baines, Kim M. ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2015年 / 21卷 / 27期

基金：

加拿大自然科学与工程研究理事会;

关键词：

gallium; bimetallic; cations; complexation; cryptand; MAIN-GROUP COMPOUNDS; CRYSTAL-STRUCTURE; UNIVALENT GALLIUM; MOLECULAR-STRUCTURE; HYDRIDE COMPLEXES; NEUTRAL COMPLEXES; DATIVE BONDS; COORDINATION; ELEMENTS; LIGANDS;

D O I：

10.1002/chem.201501345

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterization of two bimetallic, cationic low-valent gallium-cryptand[2.2.2] complexes is reported. The reaction of cryptand[2.2.2] with Ga2Cl4 gave two different cations, [Ga3Cl4(crypt-222)](+) (1) or [Ga2Cl2(crypt-222)](2+) (2), depending on whether or not tri-methylsilyl triflate (Me3SiOTf) was added as a co-reagent. Complexes 1 and 2 are the first examples of bimetallic cryptand[2.2.2] complexes, as well as the first low-valent gallium-cryptand[2.2.2] complexes. Computational methods were used to evaluate the bonding in the gallium cores.

引用

页码：9790 / 9796

页数：7

共 50 条

[31] Synthesis of Multisubstituted Cyclopentadiene Derivatives from 3,3-Disubstituted Cyclopropenes and Internal Alkynes Catalyzed by Low-Valent Niobium Complexes [J].

Akiyama, Takuya ;

Kusamoto, Tetsuro ;

Mashima, Kazushi ;

Tsurugi, Hayato .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (49) :33338-33348

[32] Redox-enabled cooperative catalysis by activating secondary alcohols using low-valent Zn complexes [J].

Samanta, Arup ;

Chaubey, Amit ;

Pal, Debjyoti ;

Majhi, Krishna ;

Srimani, Dipankar .

CHEMICAL COMMUNICATIONS, 2024, 60 (75) :10398-10401

[33] Low-Valent Ene-Amido Iron Complexes for the Asymmetric Transfer Hydrogenation of Acetophenone without Base [J].

Lagaditis, Paraskevi O. ;

Lough, Alan J. ;

Morris, Robert H. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (25) :9662-9665

[34] Direct, One-Pot Syntheses of MOFs Decorated with Low-Valent Metal-Phosphine Complexes [J].

Dunning, Samuel G. ;

Reynolds, Joseph E., III ;

Walsh, Kelly M. ;

Kristek, David J. ;

Lynch, Vincent M. ;

Kunal, Pranaw ;

Humphrey, Simon M. .

ORGANOMETALLICS, 2019, 38 (18) :3406-3411

[35] Synthesis of Low-Valent Dinuclear Group 14 Compounds with Element-Element Bonds by Transylidation [J].

Mohapatra, Chandrajeet ;

Darmandeh, Heidar ;

Steinert, Henning ;

Mallick, Bert ;

Feichtner, Kai-Stephan ;

Gessner, Viktoria H. .

CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (66) :15145-15149

[36] Synthesis and characterization of cationic rhodium(I) dicarbonyl complexes [J].

Kovach, James ;

Brennessel, William W. ;

Jones, William D. .

INORGANICA CHIMICA ACTA, 2011, 367 (01) :108-113

[37] Low-Valent Ruthenium Complexes of the Non-innocent 2,6-Bis(imino)pyridine Ligand [J].

Gallagher, Michelle ;

Wieder, Noah L. ;

Dioumaev, Vladimir K. ;

Carroll, Patrick. J. ;

Berry, Donald H. .

ORGANOMETALLICS, 2010, 29 (03) :591-603

[38] Structural diversity and solution behavior of low-valent iridium complexes bearing 1,4-diazabutadiene ligands [J].

Langer, Jens ;

Goerls, Helmar .

INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (10) :1612-1615

[39] Low-Valent Aminopyridinato Chromium Methyl Complexes via Reductive Alkylation and via Oxidative Addition of Iodomethane by a Cr-Cr Quintuple Bond [J].

Noor, Awal ;

Schwarz, Stefan ;

Kempe, Rhett .

ORGANOMETALLICS, 2015, 34 (11) :2122-2125

[40] Reduced Uranium Complexes: Synthetic and DFT Study of the Role of π Ligation in the Stabilization of Uranium Species in a Formal Low-Valent State [J].

Korobkov, Ilia ;

Gorelsky, Serge ;

Gambarotta, Sandro .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (30) :10406-10420

← 1 2 3 4 5 →