Occurrence of anthocyanin-derived pigments in red wines

被引:130
作者
Mateus, N
Silva, AMS
Vercauteren, J
de Freitas, V
机构
[1] Ctr Invest Quim, Dept Quim Porto, P-4169007 Oporto, Portugal
[2] Univ Aveiro, Dept Quim, P-3810193 Aveiro, Portugal
[3] Univ Bordeaux 2, Lab Pharmacognosie, F-33076 Bordeaux, France
关键词
red wine; aging; pigments; anthopyanins; pyruvic acid;
D O I
10.1021/jf001505b
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Several anthocyanin-derived pigments that showed UV-visible spectra different from those of the original grape anthocyanins were detected by HPLC-DAD analysis in 1-year-old bottled Port wines from the Douro region. Among these, three malvidin 3-glucoside derived pigments were detected in large amounts, representing similar to 60% of the total anthocyanidin monoglucosides content. These pigments were isolated, purified, and identified by LSI-MS and NMR (H-1, DQF-COSY, ROESY, HSQC, and HMBC) techniques. The major pigment is malvidin 3-glucoside pyruvic adduct, previously characterized, and the other two corresponded to its respective acetyl and coumaroyl glucoside derivatives. The latter is reported for the first time in red wines.
引用
收藏
页码:4836 / 4840
页数:5
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