Diels-Alder reaction with transition metal/zeolites

被引：15

作者：

Zendehdel, M ^{[1
]}

Far, NF ^{[1
]}

Gaykani, Z ^{[1
]}

机构：

[1] Arak Univ, Coll Sci, Dept Chem, Arak, Iran

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2005年 / 53卷 / 1-2期

关键词：

acid sites; Diels-Alder; ion-exchange; zeolite;

D O I：

10.1007/s10847-005-0935-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition metal/Y zeolites were prepared by microwave solid state and aqueous solution ion-exchange methods. The activity of these zeolites was investigated in a Diels-Alder reaction of cyclopentadiene and maleic anhydride, anthracene and maleic anhydride. The yield of these reactions increased in order of (NaY<Fe2+Y<Fe3+Y<MnY<CuY approximate to NiY<CoY approximate to CrY<ZnY) for both methods. The aqueous solution ion-exchanged zeolites showed higher activity in comparison to solid state exchange. About 65-70% yield was observed for the Diels-Alder reaction with ZnY Zeolite. Endo-selectivity was observed for these reactions.

引用

页码：47 / 49

页数：3

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