Oxidative rearrangement of imidazoles with dimethyldioxirane

被引：72
|
作者：
Lovely, CJ [1 ]
Du, HW [1 ]
He, Y [1 ]
Dias, HVR [1 ]
机构：
[1] Univ Texas, Dept Biochem & Chem, Arlington, TX 76019 USA
来源：
ORGANIC LETTERS | 2004年 / 6卷 / 05期
关键词：
D O I：
10.1021/ol036403w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Tetrahydrobenzimidazoles, on treatment with dimethyldioxirane, rearrange to provide 5-imidazolones exclusively. These rearrangements proceed with a broad range of substrates and with good to excellent levels of diastereoselectivity.
引用
收藏
页码：735 / 738
页数：4
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