Removal of boron from metallurgical grade silicon by electromagnetic induction slag melting

被引:55
作者
Luo Da-wei [1 ]
Liu Ning [1 ]
Lu Yi-ping [1 ]
Zhang Guo-liang [1 ]
Li Ting-ju [1 ,2 ]
机构
[1] Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China
[2] Dalian Univ Technol, Key Lab Mat Modificat Laser Ion & Electron Beams, Minist Educ, Dalian 116024, Peoples R China
基金
中国国家自然科学基金;
关键词
metallurgical grade silicon; slag system; partition ratio; POLYCRYSTALLINE SILICON;
D O I
10.1016/S1003-6326(11)60840-6
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
A new purification process was developed to remove impurities in metallurgical grade silicon (MG-Si) by electromagnetic induction slag melting (EISM). Vacuum melting furnace was used to purify boron in different slag systems. The results show that the removal effect in SiO2-CaO-Al2O3 systems is better than that in other slag systems by EISM. The boron content in MG-Si is successfully reduced from 1.5x10(-5) to 0.2x10(-5) during EISM at 1 823 K for 2 h. Meanwhile, Al, Ca and Mg elements in MG-Si are also well removed and their removal efficiencies reach 85.0%, 50.2% and 66.7%, respectively, which indicates that EISM is very effective to remove boron and metal impurities in silicon.
引用
收藏
页码:1178 / 1184
页数:7
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