Architecturally similar monomers were copolymerized with a water-oil discriminate fluorosurfactant to create hydrophilic-oleophobic coatings. Acrylic acid, hydroxyethyl methacrylate, and methyl methacrylate were used as comonomers with the fluorosurfactant macromer. The homopolymers of the selected comonomers are water-soluble, water-swellable, and water-insoluble, respectively, thus coupling the surfactant monomer in varying concentration within polymers of varying hydrophilicity. Wetting behavior of water and hexadecane were examined as a function of copolymer composition, thus revealing critical structure property relationships for the surfactant-based system. Acrylic acid copolymers and hydroxyethyl methacrylate copolymers both exhibited a hexadecane contact angle which exceeded the water contact angle. This condition predicted an ability to "self-clean" oil-based foulants. The most oleophobic of the self-cleaning copolymers had an advancing hexadecane contact angle of 73 degrees and an advancing water contact angle of 40 degrees. It was determined that the advancing and receding water and hexadecane contact angle response varies montonically for each copolymer type as the surface concentration of the surfactant is varied. Comparing between copolymer types revealed large differences in wetting response. Methyl methacrylate copolymers with 2.8 mol % surfactant had advancing water contact angle 82 degrees and advancing hexadecane contact angle 26 degrees, which is neither oleophobic nor self-cleaning. In contrast, acrylic acid copolymers with 3.1 mol % surfactant had advancing water contact angle of 44 degrees and advancing hexadecan contact angle of 52 degrees, creating a self-cleaning coating. Thus, the nature of the comonomer exerts a greater influence than the surfactant content on the wetting behavior and self-cleaning ability of the final coating.
机构:
Univ Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, France
CEA Saclay, Lab Leon Brillouin, F-91191 Gif Sur Yvette, FranceUniv Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, France
Al Akhrass, Samer
;
Damiron, Denis
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Univ Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, FranceUniv Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, France
Damiron, Denis
;
Carrot, Geraldine
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CEA Saclay, Lab Leon Brillouin, F-91191 Gif Sur Yvette, FranceUniv Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, France
Carrot, Geraldine
;
Drockenmuller, Eric
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Univ Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, FranceUniv Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, France
机构:
Univ Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, MalaysiaUniv Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, Malaysia
Amin, Indok Nurul Hasyimah Mohd
;
Mohammad, Abdul Wahab
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Univ Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, MalaysiaUniv Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, Malaysia
Mohammad, Abdul Wahab
;
Markom, Mastura
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Univ Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, MalaysiaUniv Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, Malaysia
Markom, Mastura
;
Peng, Leo Choe
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Univ Sains Malaysia, Sch Chem Engn, Perai, Pulau Pinang, MalaysiaUniv Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, Malaysia
机构:
Univ Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, France
CEA Saclay, Lab Leon Brillouin, F-91191 Gif Sur Yvette, FranceUniv Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, France
Al Akhrass, Samer
;
Damiron, Denis
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h-index: 0
机构:
Univ Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, FranceUniv Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, France
Damiron, Denis
;
Carrot, Geraldine
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机构:
CEA Saclay, Lab Leon Brillouin, F-91191 Gif Sur Yvette, FranceUniv Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, France
Carrot, Geraldine
;
Drockenmuller, Eric
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Univ Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, FranceUniv Lyon 1, CNRS, UMR 5223, IMP, F-69622 Villeurbanne, France
机构:
Univ Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, MalaysiaUniv Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, Malaysia
Amin, Indok Nurul Hasyimah Mohd
;
Mohammad, Abdul Wahab
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机构:
Univ Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, MalaysiaUniv Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, Malaysia
Mohammad, Abdul Wahab
;
Markom, Mastura
论文数: 0引用数: 0
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机构:
Univ Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, MalaysiaUniv Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, Malaysia
Markom, Mastura
;
Peng, Leo Choe
论文数: 0引用数: 0
h-index: 0
机构:
Univ Sains Malaysia, Sch Chem Engn, Perai, Pulau Pinang, MalaysiaUniv Kebangsaan Malaysia, Dept Chem & Proc Engn, Fac Engn & Built Environm, Bangi 43600, Selangor, Malaysia