Synthesis and structure of a Ni(II) complex with N′,N′2-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH ••• π interactions between quinoline and quinolineimine chelate

被引：5

作者：

Cobeljic, Bozidar ^{[1
]}

Warzajtis, Beata ^{[2
]}

Rychlewska, Urszula ^{[2
]}

Radanovic, Dusanka ^{[3
]}

Spasojevic, Vojislav ^{[4
]}

Sladic, Dusan ^{[1
]}

Eshkourfu, Rabia ^{[1
]}

Andelkovic, Katarina ^{[1
]}

机构：

[1] Univ Belgrade, Fac Chem, Belgrade 11000, Serbia

[2] Adam Mickiewicz Univ Poznan, Fac Chem, PL-60780 Poznan, Poland

[3] Univ Belgrade, Inst Chem Technol & Met, Belgrade 11000, Serbia

[4] Inst Nucl Sci Vinca, Condensed Matter Phys Lab, Belgrade 11000, Serbia

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 65卷 / 04期

关键词：

Ni(II) complexes; X-ray structure; Intramolecular interactions; TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURES; NICKEL(II) COMPLEXES; MAGNETIC-PROPERTIES; CYTOTOXIC ACTIVITY; HYDRAZONE LIGANDS; SCHIFF-BASE; CU(II); DATABASE; ZINC(II);

D O I：

10.1080/00958972.2012.658778

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new malonic dihydrazide-based ligand, N',N'(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide (H(2)L3), has been prepared and characterized by elemental analysis, IR, C-13 NMR, and H-1 NMR spectroscopies. In the reaction of H(2)L3 with Ni(II) a binuclear complex has been obtained. The structure of the complex was established by X-ray analysis. Each Ni(II) is coordinated with two NNO donor sets from two ligand molecules in dianionic form (L3(2-)) forming an octahedral geometry. Multiple intramolecular C-H center dot center dot center dot pi (chelate ring) interactions support the molecular geometry of the [Ni-2(L3)(2)] complex. The structure of [Ni-2(L3)(2)] is compared with those of analogous Ni(II) complexes with pyridine dihydrazone type ligands. Magnetic behavior of the dinuclear complex was studied in temperature range of 2-300 K.

引用

页码：655 / 667

页数：13

共 32 条

[1] Synthesis, characterization and X-ray crystallographic structural study of copper(II) and nickel(II) complexes of the 2-quinoline carboxaldehyde Schiff base of S-methyldithiocarbazate (Hqaldsme)
Ali, M. Akbar
Mirza, A. H.
Bujan, Fatriah Hj
Hamid, Malai Haniti S. A.
Bernhardt, Paul V.
[J]. POLYHEDRON, 2006, 25 (17) : 3245 - 3252
[2] The Cambridge Structural Database: a quarter of a million crystal structures and rising
Allen, FH
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1): : 380 - 388
[3] THE DEVELOPMENT OF VERSION-3 AND VERSION-4 OF THE CAMBRIDGE STRUCTURAL DATABASE SYSTEM
ALLEN, FH
DAVIES, JE
GALLOY, JJ
JOHNSON, O
KENNARD, O
MACRAE, CF
MITCHELL, EM
MITCHELL, GF
SMITH, JM
WATSON, DG
[J]. JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1991, 31 (02): : 187 - 204
[4] Complexes of iron(II), iron(III) and zinc(II) with condensation derivatives of 2-acetylpyridine and oxalic or malonic dihydrazide.: Crystal structure of tris[(1-(2-pyridyl)ethylidene)hydrazine]iron(II) perchlorate
Andelkoviç, K
Sladic, D
Bacchi, A
Pelizzi, G
Filipoviç, N
Rajkovic, M
[J]. TRANSITION METAL CHEMISTRY, 2005, 30 (02) : 243 - 250
[5] [Anonymous], 1990, XP
[6] Ni(II), Cu(II), and Zn(II) dinuclear metal complexes with an aza-phenolic ligand: Crystal structures, magnetic properties, and solution studies
Berti, E
Caneschi, A
Daiguebonne, C
Dapporto, P
Formica, M
Fusi, V
Giorgi, L
Guerri, A
Micheloni, M
Paoli, P
Pontellini, R
Rossi, P
[J]. INORGANIC CHEMISTRY, 2003, 42 (02) : 348 - 357
[7] New software for searching the Cambridge Structural Database and visualizing crystal structures
Bruno, IJ
Cole, JC
Edgington, PR
Kessler, M
Macrae, CF
McCabe, P
Pearson, J
Taylor, R
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2002, 58 : 389 - 397
[8] Magnetic [n x n] (n=2-5) Grids by Directed Self-Assembly
Dawe, Louise N.
Shuvaev, Konstantin V.
Thompson, Laurence K.
[J]. INORGANIC CHEMISTRY, 2009, 48 (08) : 3323 - 3341
[9] Supramolecular self-assembled polynuclear complexes from tritopic, tetratopic, and pentatopic ligands: Structural, magnetic and surface studies
Dey, Subrata K.
Abedin, Tareque S. M.
Dawe, Louise N.
Tandon, Santokh S.
Collins, Julie L.
Thompson, Laurence K.
Postnikov, Andrei V.
Alam, Mohammad S.
Muller, Paul
[J]. INORGANIC CHEMISTRY, 2007, 46 (19) : 7767 - 7781
[10] Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N′,N′2-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide
Filipovic, Nenad R.
Bacchi, Alessia
Lazic, Milan
Pelizzi, Giancarlo
Radulovic, Sinisa
Sladic, Dusan M.
Todorovic, Tamara R.
Andelkovic, Katatina K.
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (01) : 47 - 50

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