Anthraceno-Perylene Bisimides: The Precursor of a New Acene

被引:62
作者
Li, Yongjun [1 ]
Xu, Liang
Liu, Taifeng
Yu, Yanwen
Liu, Huibiao
Li, Yuliang
Zhu, Daoben
机构
[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci BNLMS, Beijing 100190, Peoples R China
关键词
SYNTHETIC APPROACH; HEPTACENE; DYES; DERIVATIVES; PHOTOGENERATION; SEMICONDUCTORS; PENTACENE; HEXACENE; NONACENE; DESIGN;
D O I
10.1021/ol202417u
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A controlled synthesis strategy for a anthracene-fused perylene bisimide was developed from the cyclization of an anthracene unit pendant to a perylene diimide scaffold. The direct cyclization led to a zigzag molecule, while a Diels-Alder strategy influenced the reglochemistry of cyclization to afford the linear precursor of a new acene.
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收藏
页码:5692 / 5695
页数:4
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