Nanocomposite of polypyrrole and alumina nanoparticles as a coating filler for the corrosion protection of aluminium alloy 2024-T3

Aluminium (Al) alloys such as 2024-T3 are widely used in industry as low weight construction materials with excellent mechanical properties. Until recently corrosion protection of Al alloys was carried out with coatings containing hexavalent chromium (Cr(6+)). However, Cr(6+) is a health and environmental hazard and has to be replaced. Intrinsically conducting polymer (ICP) technology is the promising alternative to chromate coating technology because of good corrosion protection properties of ICPs, their moderate cost and good environmental compatibility. In this paper we report successful attempt of making nanocomposite comprised of alumina nanoparticles modified by polypyrrole for the purpose of corrosion protection of Al alloy. Modified nanoparticles were used as coating filler. Coating was designated to perform as an active barrier to electrolyte diffusion. Properties of the coating were examined by adhesion test, electrochemical impedance spectroscopy, X-rays elemental analysis, scanning electron microscopy, transmission electron microscopy, and Fourier transform infrared spectroscopy. (C) 2008 Elsevier B.V. All rights reserved.