AC conductivity and dielectric behavior of low-temperature phase of α-AgCuPO4

被引:10
作者
Mansour, S. Ouled [1 ]
Louati, B. [1 ]
Guidara, K. [1 ]
机构
[1] Univ Sfax, Fac Sci, Condensed Matter Lab, BP 1171, Sfax 3000, Tunisia
关键词
Rietveld analysis; Dielectric properties; Electrical properties; AC conductivity; DEPENDENCE; SPECTRA;
D O I
10.1007/s11581-015-1632-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The copper monophosphate compound, alpha-AgCuPO4, was prepared by the conventional solid-state reaction. The purity of the compound was checked by X-ray diffraction technique (XRD). Detailed dielectric and electrical properties of the compound were analyzed as a function of frequency (209 Hz-1 MHz) and temperature (343-514 K). The AC conductivity has been fitted and studied using Jonscher's equation, whose exponent n varied with the temperature, showing that the overlapping large polaron tunneling model (OLPT) is the appropriate model to describe the electrical conduction mechanism.
引用
收藏
页码:1135 / 1143
页数:9
相关论文
共 39 条
[1]   Conductivity and dielectric studies on K2SrP2O7 compound [J].
Ajili, O. ;
Louati, B. ;
Guidara, K. .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2015, 119 (03) :1119-1125
[2]   ANOMALOUS CONDUCTIVITY PREFACTORS IN FAST ION CONDUCTORS [J].
ALMOND, DP ;
WEST, AR .
NATURE, 1983, 306 (5942) :456-457
[3]   POLARONS IN CRYSTALLINE AND NON-CRYSTALLINE MATERIALS [J].
AUSTIN, IG ;
MOTT, NF .
ADVANCES IN PHYSICS, 1969, 18 (71) :41-+
[4]   A high-pressure, Raman spectroscopic study of bis(pyrophosphato)tetrazinc(II) arid-tetramanganese(II) decahydrate salts [J].
Baril, Martin ;
Assaaoudi, Hassane ;
Kozinski, Janusz A. ;
Butler, Ian S. .
INORGANICA CHIMICA ACTA, 2007, 360 (10) :3155-3161
[5]   A.c. conductivity and dielectric study of LiNiPO4 synthesized by solid-state method [J].
Ben Bechir, M. ;
Ben Rhaiem, A. ;
Guidara, K. .
BULLETIN OF MATERIALS SCIENCE, 2014, 37 (03) :473-480
[6]   Electrical conduction and thermodynamic properties of K2NiP2O7 [J].
Ben Said, R. ;
Louati, B. ;
Guidara, K. .
IONICS, 2014, 20 (02) :209-219
[7]   Comparison of the crystal structures and magnetic properties of the low- and high-temperature forms of AgCuPO4:: Crystal structure determination, magnetic susceptibility measurements, and spin dimer analysis [J].
Ben Yahia, Hamdi ;
Gaudin, Etienne ;
Darriet, Jacques ;
Dai, Dadi ;
Whangbo, Myung-Hwan .
INORGANIC CHEMISTRY, 2006, 45 (14) :5501-5509
[8]   General susceptibility functions for relaxations in disordered systems [J].
Bergman, R .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (03) :1356-1365
[9]  
Bouhaouss A., 2001, PHYS CHEM NEWS, V1, P125
[10]   FERROELASTIC BEHAVIOR OF NDXLA1-XP5O14 CRYSTALS [J].
BUDIN, JP ;
MILATOSROUFOS, A ;
DUCHINH, N ;
LEROUX, G .
JOURNAL OF APPLIED PHYSICS, 1975, 46 (07) :2867-2872