Surface modification of Li2ZnTi3O8 with the C&N layer for lithium-ion batteries

被引:10
作者
Chen, Chi [1 ]
Li, Zhuye [1 ]
Xu, Baoming [1 ]
机构
[1] Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Hubei, Peoples R China
关键词
Lithium-ion batteries; Li2ZnTi3O8; C&N layer; Electronic conductivity; Electrochemical performance; ZINC TITANATE ANODE; LONG CYCLE LIFE; DOPED CARBON; ELECTROCHEMICAL PERFORMANCE; RATE CAPABILITY; IN-SITU; NITROGEN; NANOCOMPOSITE; NANOPARTICLES; LI2MNTI3O8;
D O I
10.1016/j.matchemphys.2020.122718
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The C&N coated Li2ZnTi3O8 is synthesized by heat-treating pristine Li2ZnTi3O8 and urea (CO(NH2)(2)) at 400 degrees C for a short time. The content of the C&N layer of the C&N coated Li2ZnTi3O8 is similar to 3.5 wt% and the N content of 2.06 wt% is achieved. After coupling with a C&N layer, the C&N coated Li2ZnTi3O8 delivers a discharge specific capacity of 230.1, 211.9, 197.4, 190.6 and 180.4 mAh g(-1) after 10 cycles at the current density of 0.1, 0.5, 1.5, 2.5 and 4.0 A g(-1), respectively, and exhibits a remarkable stability over 400 cycles at 1.5 A g(-1). The effect of the formed C&N layer on the structure and electrochemical properties of the C&N coated Li2ZnTi3O8 has been characterized by a series of means.
引用
收藏
页数:8
相关论文
共 43 条
[31]   Carbon-pore-sheathed cobalt nanoseeds: An exceptional and durable bifunctional catalyst for zinc-air batteries [J].
Xing, Zhenyu ;
Deng, Ya-Ping ;
Sy, Serubbabel ;
Tan, Guoqiang ;
Li, Aiju ;
Li, Jingde ;
Niu, Yue ;
Li, Na ;
Su, Dong ;
Lu, Jun ;
Chen, Zhongwei .
NANO ENERGY, 2019, 65
[32]   A Brief Review of Metallothermic Reduction Reactions for Materials Preparation [J].
Xing, Zhenyu ;
Lu, Jun ;
Ji, Xiulei .
SMALL METHODS, 2018, 2 (12)
[33]   Recessed deposition of TiN into N-doped carbon as a cathode host for superior Li-S batteries performance [J].
Xing, Zhenyu ;
Li, Gaoran ;
Sy, Serubbabel ;
Chen, Zhongwei .
NANO ENERGY, 2018, 54 :1-9
[34]   Nitrogen-Doped Nanoporous Graphenic Carbon: An Efficient Conducting Support for O2 Cathode [J].
Xing, Zhenyu ;
Luo, Xiangyi ;
Qi, Yitong ;
Stickle, William F. ;
Amine, Khalil ;
Lu, Jun ;
Ji, Xiulei .
CHEMNANOMAT, 2016, 2 (07) :692-697
[35]   One step sol-gel synthesis of Li2ZnTi3O8/C nanocomposite with enhanced lithium-ion storage properties [J].
Xu, Yuxia ;
Hong, Zhensheng ;
Xia, Lunchao ;
Yang, Jie ;
Wei, Mingdeng .
ELECTROCHIMICA ACTA, 2013, 88 :74-78
[36]   Novel understanding of carbothermal reduction enhancing electronic and ionic conductivity of Li4Ti5O12 anode [J].
Yan, Bo ;
Li, Minsi ;
Li, Xifei ;
Bai, Zhimin ;
Yang, Jianwen ;
Xiong, Dongbin ;
Li, Dejun .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (22) :11773-11781
[37]   Graphene-encapsulated Li2MnTi3O8 nanoparticles as a high rate anode material for lithium-ion batteries [J].
Yang, Le ;
Zhang, Xinyi ;
Li, Yue ;
Hao, Feng ;
Chen, Haosen ;
Yang, Meng ;
Fang, Daining .
ELECTROCHIMICA ACTA, 2015, 155 :272-278
[38]   A Sustainable Route from Biomass Byproduct Okara to High Content Nitrogen-Doped Carbon Sheets for Efficient Sodium Ion Batteries [J].
Yang, Tingzhou ;
Qian, Tao ;
Wang, Mengfan ;
Shen, Xiaowei ;
Xu, Na ;
Sun, Zhouzhou ;
Yan, Chenglin .
ADVANCED MATERIALS, 2016, 28 (03) :539-+
[39]   Conductive surface modification of LiFePO4 with nitrogen-doped carbon layers for lithium-ion batteries [J].
Yoon, Sukeun ;
Liao, Chen ;
Sun, Xiao-Guang ;
Bridges, Craig A. ;
Unocic, Raymond R. ;
Nanda, Jagjit ;
Dai, Sheng ;
Paranthaman, M. Parans .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (11) :4611-4614
[40]   Hierarchical hollow microspheres assembled from N-doped carbon coated Li4Ti5O12 nanosheets with enhanced lithium storage properties [J].
Zhang, Zhonghua ;
Li, Guicun ;
Peng, Hongrui ;
Chen, Kezheng .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (48) :15429-15434