共 43 条
Surface modification of Li2ZnTi3O8 with the C&N layer for lithium-ion batteries
被引:10
作者:

Chen, Chi
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机构:
Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Hubei, Peoples R China Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Hubei, Peoples R China

Li, Zhuye
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Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Hubei, Peoples R China Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Hubei, Peoples R China

Xu, Baoming
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Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Hubei, Peoples R China Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Hubei, Peoples R China
机构:
[1] Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Hubei, Peoples R China
关键词:
Lithium-ion batteries;
Li2ZnTi3O8;
C&N layer;
Electronic conductivity;
Electrochemical performance;
ZINC TITANATE ANODE;
LONG CYCLE LIFE;
DOPED CARBON;
ELECTROCHEMICAL PERFORMANCE;
RATE CAPABILITY;
IN-SITU;
NITROGEN;
NANOCOMPOSITE;
NANOPARTICLES;
LI2MNTI3O8;
D O I:
10.1016/j.matchemphys.2020.122718
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
The C&N coated Li2ZnTi3O8 is synthesized by heat-treating pristine Li2ZnTi3O8 and urea (CO(NH2)(2)) at 400 degrees C for a short time. The content of the C&N layer of the C&N coated Li2ZnTi3O8 is similar to 3.5 wt% and the N content of 2.06 wt% is achieved. After coupling with a C&N layer, the C&N coated Li2ZnTi3O8 delivers a discharge specific capacity of 230.1, 211.9, 197.4, 190.6 and 180.4 mAh g(-1) after 10 cycles at the current density of 0.1, 0.5, 1.5, 2.5 and 4.0 A g(-1), respectively, and exhibits a remarkable stability over 400 cycles at 1.5 A g(-1). The effect of the formed C&N layer on the structure and electrochemical properties of the C&N coated Li2ZnTi3O8 has been characterized by a series of means.
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