Functionalization and photoelectrochemical characterization of poly [3-3′(vinylcarbazole)] multi-walled carbon nanotube (PVK-MWNT) Langmuir-Schaefer films

被引:28
作者
Bertoncello, P
Notargiacomo, A
Erokhin, V
Nicolini, C
机构
[1] Univ Genoa, Nanoworld Inst, I-16132 Genoa, Italy
[2] Univ Genoa, Div Biophys, I-16132 Genoa, Italy
[3] Univ Rome TRE, Dept Phys, I-00146 Rome, Italy
[4] Univ Rome TRE, INFM, I-00146 Rome, Italy
[5] CNR, Ist Sistemi Complessi, Ctr SOFT, Rome, Italy
[6] Univ Parma, Dept Phys, I-43100 Parma, Italy
关键词
D O I
10.1088/0957-4484/17/3/014
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Multi-walled carbon nanotubes (MWNTs) were functionalized via oxidative polymerization of 3-3'(vinylcarbazole) (PVK). Thin films of PVK-functionalized MWNTs (PVK-MWNTs) were fabricated by the Langmuir-Schaefer (LS) technique and characterized by spectroscopic, microscopic, electrical and electrochemical techniques before and after doping with iodine. I/V characterization showed an increase in the conductivity of the PVK-MWNTs and I-2-doped PVK-MWNTs compared with the PVK and I-2-doped PVK, respectively. The electrochemical characterization showed the formation of an I-2-doped PVK-MWNT complex. These nanostructured PVK-MWNT films revealed an increase in the current density under illumination of about 500 nA cm(-2).
引用
收藏
页码:699 / 705
页数:7
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