Novel non-aggregated soluble metallophthalocyanines bearing carboxylic acid groups

被引：11

作者：

Bayar, Serife ^{[1
]}

Dincer, Hatice A. ^{[1
]}

Ugur, Ahmet L. ^{[2
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

[2] Yildiz Tekn Univ, Dept Chem, TR-34210 Istanbul, Turkey

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 65卷 / 08期

关键词：

Phthalocyanine; Carboxylic acid; Hydrolysis; Absorption; Aggregation; Polar solvent; EXCITED-STATE DYNAMICS; ZINC PHTHALOCYANINES; WATER; MACROCYCLES; PHOTOCATALYSTS; SUBSTITUENTS; OXIDATION; THERAPY; CELLS; TUMOR;

D O I：

10.1080/00958972.2012.673124

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis and characterization of zinc and cobalt phthalocyanines substituted with biphenylmethylpropionic acids, methyl-o-tolylpropionic acids, and methyl-p-tolylpropionic acids are described in this study. The new compounds have been characterized by elemental analyses, FT-IR, UV-Vis, MALDI-TOF, and H-1 NMR spectroscopy. All new compounds are soluble in THF, DMF, DMSO, and dilute sodium hydroxide solution. The influence of the carboxylic acid and bulky biphenyl, ortho-methylbenzyl and para-methylbenzyl groups on the spectroscopic properties has been investigated. UV-Vis experiments suggest that the tendency of phthalocyanines to aggregate in polar solvents is significantly reduced owing to the carboxylic acid groups and bulky peripheral substituents.

引用

页码：1371 / 1380

页数：10

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