Efficient conversion of D-glucose into D-sorbitol over MCM-41 supported Ru catalyst prepared by a formaldehyde reduction process

被引：55

作者：

Zhang, Jun ^{[1
]}

Lin, Lu ^{[1
]}

Zhang, Junhua ^{[1
]}

Shi, Jianbin ^{[1
]}

机构：

[1] S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

CARBOHYDRATE RESEARCH | 2011年 / 346卷 / 11期

关键词：

Ru/MCM-41; Hydrogenation; D-Glucose; Mechanism; TRICKLE-BED REACTOR; RANEY-TYPE NI; RUTHENIUM CATALYSTS; SELECTIVE HYDROGENATION; NICKEL; PHASE;

D O I：

10.1016/j.carres.2011.04.037

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Ru/MCM-41 catalyst prepared by an impregnation-formaldehyde reduction method showed higher catalytic activity and sorbitol selectivity than other catalysts in the hydrogenation of glucose. SEM and XRD indicated the partial surface properties of Ru/MCM-41. Moreover, Ru dispersion and Ru surface area of Ru/MCM-41 were determined by pulse chemisorption, and the result further proved that Ru/MCM-41 had higher catalytic activity. A catalyst recycling experiment demonstrated that Ru/MCM-41 was a better catalyst and it could be reused three or four times. A speculated mechanism was proposed to illustrate the detailed process of D-glucose hydrogenation to produce sorbitol. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：1327 / 1332

页数：6

共 20 条

[1] Efficient Conversion of D-Glucose into D-Sorbitol over Carbonized Cassava Dregs-Supported Ruthenium Nanoparticles Catalyst
Li, Zengyong
Liu, Ying
Wu, Shubin
BIORESOURCES, 2018, 13 (01): : 1278 - 1288
[2] Ru-B amorphous alloy deposited on mesoporous silica nanospheres: An efficient catalyst for D-glucose hydrogenation to D-sorbitol
Wang, Senlin
Wei, Wei
Zhao, Yu
Li, Hexing
Li, Hui
CATALYSIS TODAY, 2015, 258 : 327 - 336
[3] Selective hydrogenation of D-glucose to D-sorbitol over Ru/ZSM-5 catalysts
Guo, Xingcui
Wang, Xicheng
Guan, Jing
Chen, Xiufang
Qin, Zhangfeng
Mu, Xindong
Xian, Mo
CHINESE JOURNAL OF CATALYSIS, 2014, 35 (05) : 733 - 740
[4] Bimetallic Ru:Ni/MCM-48 catalysts for the effective hydrogenation of D-glucose into sorbitol
Romero, Alberto
Nieto-Marquez, Antonio
Alonso, Esther
APPLIED CATALYSIS A-GENERAL, 2017, 529 : 49 - 59
[5] An Integrated Process for D-Sorbitol Production over NiO/TiO2 Supported Ru Nanocatalyst: A Greener Approach
Mishra, Dinesh Kumar
Truong, Cong Chien
Dabbawala, Aasif Asharaf
Hwang, Jin-Soo
TOPICS IN CATALYSIS, 2023, 66 (1-4) : 223 - 234
[6] Highly efficient metal catalysts supported on activated carbon cloths: A catalytic application for the hydrogenation of D-glucose to D-sorbitol
Perrard, Alain
Gallezot, Pierre
Joly, Jean-Pierre
Durand, Robert
Baljou, Udric
Coq, Bernard
Trens, Philippe
APPLIED CATALYSIS A-GENERAL, 2007, 331 (01) : 100 - 104
[7] Liquid phase hydrogenation of D-glucose to D-sorbitol over the catalyst (Ru/NiO-TiO2) of ruthenium on a NiO-modified TiO2 support
Mishra, Dinesh Kumar
Lee, Jong-Min
Chang, Jong-San
Hwang, Jin-Soo
CATALYSIS TODAY, 2012, 185 (01) : 104 - 108
[8] Preparation of D-Sorbitol by Catalytic Hydrogenation of D-Glucose with Semi Sandwich Iridium Catalyst
Gong, Baoxiang
Yan, Long
Chen, Mengyuan
Deng, Jin
Fu, Yao
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (12) : 3170 - 3176
[9] Conversion of biomass into sorbitol: Cellulose hydrolysis on MCM-48 and D-Glucose hydrogenation on Ru/MCM-48
Romero, Alberto
Alonso, Esther
Sastre, Alvaro
Nieto-Marquez, Antonio
MICROPOROUS AND MESOPOROUS MATERIALS, 2016, 224 : 1 - 8
[10] One-Pot Catalytic Conversion of Cellobiose to Sorbitol over Nickel Phosphides Supported on MCM-41 and Al-MCM-41
Anutrasakda, Wipark
Eiamsantipaisarn, Kanyanok
Jiraroj, Duangkamon
Phasuk, Apakorn
Tuntulani, Thawatchai
Liu, Haichao
Tungasmita, Duangamol Nuntasri
CATALYSTS, 2019, 9 (01)

← 1 2 →