Facile Construction of Magnetic Ionic Liquid Supported Silica for Aerobic Oxidative Desulfurization in Fuel

被引:1
|
作者
Liu, Fujie [1 ]
Zhang, Ming [2 ]
Gao, Yongkang [2 ]
Tan, Haojie [2 ]
Li, Hongping [2 ]
Wang, Chao [3 ]
Zhu, Wenshuai [2 ]
Li, Huaming [2 ]
机构
[1] Zhenjiang Coll, Inst Med & Chem Engn, Zhenjiang Key Lab Funct Chem, Zhenjiang 212028, Jiangsu, Peoples R China
[2] Jiangsu Univ, Inst Energy Res, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China
[3] Jiangsu Univ, Jingjiang Coll, Zhenjiang 212114, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
polyoxometalate; ionic liquid; silica; magnetic materials; ball milling; ULTRA-DEEP DESULFURIZATION; ONE-POT SYNTHESIS; SELECTIVE OXIDATION; MESOPOROUS SILICA; CALCINATION TEMPERATURE; HETEROGENEOUS CATALYSTS; HYDROGEN-PEROXIDE; DIESEL; HYDRODESULFURIZATION; DIBENZOTHIOPHENE;
D O I
10.3390/catal11121496
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With the rapid growth in fuel demand, deep desulfurization of fuel oil is vitally necessary for the sake of health and environmental protection. In this work, a kind of magnetic ionic liquid supported silica is prepared by a facile ball milling method, and applied in the aerobic oxidative desulfurization of organosulfurs in fuel. The experimental results indicated that ball milling procedure can increase the specific surface area of samples, which is beneficial to oxidative desulfurization process. Under the optimal reaction conditions, the prepared materials can have an entire removal of aromatic sulfur compounds as well as a good recycling ability. Moreover, the introduction of Fe3O4 did not decline the desulfurization performance, but help the catalyst to be easily separated after reaction.
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页数:13
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