Magnetic biochar derived from macroalgal Sargassum hemiphyllum for highly efficient adsorption of Cu(II): Influencing factors and reusability

被引:32
作者
Truong, Quoc-Minh [1 ,2 ]
Ho, Phung-Ngoc-Thao [1 ]
Nguyen, Thanh-Binh [1 ]
Chen, Wei-Hsin [3 ,4 ,5 ]
Bui, Xuan-Thanh [6 ,7 ]
Patel, Anil Kumar [8 ]
Singhania, Reeta Rani [8 ]
Chen, Chiu-Wen [8 ]
Dong, Cheng-Di [8 ]
机构
[1] Natl Kaohsiung Univ Sci & Technol, Inst Aquat Sci & Technol, Kaohsiung 81157, Taiwan
[2] Thu Dau Mot Univ, Fac Management Sci, Thu Dau Mot 75000, Binh Duong, Vietnam
[3] Natl Cheng Kung Univ, Dept Aeronaut & Astronaut, Tainan 701, Taiwan
[4] Tunghai Univ, Res Ctr Smart Sustainable Circular Econ, Taichung 407, Taiwan
[5] Natl Chin Yi Univ Technol, Dept Mech Engn, Taichung 411, Taiwan
[6] Vietnam Natl Univ Ho Chi Minh VNU HCM, Ho Chi Minh City Univ Technol HCMUT, Key Lab Adv Waste Treatment Technol, Ho Chi Minh City 700000, Vietnam
[7] Ho Chi Minh City Univ Technol HCMUT, Fac Environm & Nat Resources, 268 Ly Thuong Kiet St,Dist 10, Ho Chi Minh City 700000, Vietnam
[8] Natl Kaohsiung Univ Sci & Technol, Dept Marine Environm Engn, Kaohsiung 81157, Taiwan
关键词
Algae; Magnetic biochar; Cu (II); Iron oxide; Adsorption; COPPER IONS; MECHANISMS; KINETICS; BEHAVIOR; REMOVAL; LEAD;
D O I
10.1016/j.biortech.2022.127732
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
In this study, the brown algae Sargassum Hemiphyllum was used as a carbon source for synthesis of magnetic porous biochar via pyrolyzing at high temperature and and doping iron oxide particles (Fe-BAB). Cu (II) species were removed from aqueous solutions using Fe-BAB under various conditions. Fe-BAB demonstrated superior Cu (II) adsorption (105.3 mg g(-1)) compared to other biochars. On the surface of Fe-BAB, there are several oxygen -containing functional groups, such as -COOH and -OH, which are likely responsible for the excellent heavy metal removal performance. By utilizing magnet, the Fe-BAB can be conveniently separated from the solution and ready for further usage. Multi-adsorption mechanisms were responsible for Cu adsorption on Fe-BAB. Using the magnetic algal biochar for heavy metal removal is feasible due to its high adsorption efficiency and simplicity of separation.
引用
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页数:10
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