Trialkyl borate assisted amination of fluorinated 1,3-diketones for synthesis of N,N′-1,2-phenylen-bis(β-aminoenones) and their Ni(II), Cu(II) and Pd(II) complexes

被引：12

作者：

Chizhov, Dmitrii L. ^{[1
]}

Pervova, Marina G. ^{[1
]}

Samorukova, Mariya A. ^{[1
]}

Khmara, Ekaterina F. ^{[1
]}

Filyakova, Vera I. ^{[1
]}

Saloutin, Viktor I. ^{[1
]}

Charushin, Valery N. ^{[1
]}

机构：

[1] I Ya Postovsky Inst Organ Synth RAS, Ural Div, Ekaterinburg 620990, Russia

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2011年 / 132卷 / 06期

关键词：

Amination; Fluorinated ligands; Complexes; Gas-chromatography-mass-spectrometry; SCHIFF-BASES; METAL-COMPLEXES; COPPER(II) COMPLEXES; MAGNETIC-RESONANCE; GAS-CHROMATOGRAPHY; NICKEL(II); 1,2-DIAMINOETHANE; ETHYLENEDIAMINE; LIGANDS; MOCVD;

D O I：

10.1016/j.jfluchem.2011.03.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An effecient synthetic method for fluorinated tridentate beta-aminoenones and tetradentate bis(beta-aminoenones) via amination of fluorinated 1,3-diketones with o-phenylenediamine in the presence of trialkyl borates was developed. Ni(II), Cu(II) and Pd(II) complexes with tetradentate bis(beta-aminoenones) were obtained. Their gaschromatographic behaviour and main fragmentation paths in the electron ionization mass spectra were described. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：394 / 401

页数：8

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