Polyacrylonitrile-sulfolane-CuX2 (X = Cl, Br, CF3SO3) solid polymer electrolyte

被引：6
|
作者：
Lewandowski, A [1 ]
Stepniak, I [1 ]
机构：
[1] Poznan Univ Technol, Inst Chem, PL-60965 Poznan, Poland
来源：
SOLID STATE IONICS | 2001年 / 140卷 / 3-4期
关键词：
solid electrolyte; copper(II); impedance spectra;
D O I：
10.1016/S0167-2738(01)00824-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of polyacrylonitrile-sulfolane-CuX2 (PAN-TMS-CuX2, where X = Cl, Br, CF3SO3) polymer electrolytes, of thickness between 0.03 and 0.07 cm, were prepared by means of the solution cast technique. The solvent content was as high as 60-70 wt.%. Conductivities of the foils obtained from impedance measurements were of the order of 10(-3) Ohm (-1) cm(-1) Temperature variation of the conductivity for all the systems studied was of the Arrhenius type. Exchange current density at the Cu I electrolyte interface, determined from the Tafel plot, was of the order of milliampere (mA). Cyclic voltammetry showed the irreversible character of the copper plating-stripping process. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：361 / 367
页数：7
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