Synthesis and Properties of Diblock Copolymers Containing Poly(3-Hexylthiophene) and Poly(Fluorooctyl Methacrylate)

被引：1

作者：

Rashid, Md Harun-Or ^{[1
]}

Seo, Myungeun ^{[2
]}

Kim, Sang Youl ^{[2
]}

Gal, Yeong-Soon ^{[3
]}

Lim, Kwon Taek ^{[1
]}

机构：

[1] Pukyong Natl Univ, Div Image & Informat Engn, Pusan 608739, South Korea

[2] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea

[3] Kyungil Univ, Coll Engn, Polymer Chem Lab, Gyeongsangbuk Do 712701, South Korea

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2011年 / 11卷 / 02期

关键词：

ATRP; 1H; 1H-Perfluorooctyl Methacrylate; Poly (3-Hexylthiophene); Block Copolymer; BLOCK-COPOLYMERS; SOLAR-CELLS; REGIOREGULAR POLYTHIOPHENE; ELECTRICAL-CONDUCTIVITY; FACILE SYNTHESIS; POLYMERIZATION;

D O I：

10.1166/jnn.2011.3330

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study reports the synthesis of regioregular poly(3-hexylthiophene)-b-poly(1H,1H-dihydro perfluorooctyl methacrylate) (P3HT-b-PFOMA) block copolymers by atom transfer radical polymerization of FOMA using P3HT macroinitiators. The P3HT macroinitiator was previously prepared by chemical modification of hydroxy terminated P3HT. The block copolymers were characterized by H-1-NMR, C-13-NMR, GPC, DSC, TGA and TEM. The block copolymers are able to self-assemble into phase separated micellar thin film morphology from chloroform.

引用

页码：1696 / 1700

页数：5

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