Synthesis and Properties of Diblock Copolymers Containing Poly(3-Hexylthiophene) and Poly(Fluorooctyl Methacrylate)

被引：1
作者：
Rashid, Md Harun-Or [1 ]
Seo, Myungeun [2 ]
Kim, Sang Youl [2 ]
Gal, Yeong-Soon [3 ]
Lim, Kwon Taek [1 ]
机构：
[1] Pukyong Natl Univ, Div Image & Informat Engn, Pusan 608739, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
[3] Kyungil Univ, Coll Engn, Polymer Chem Lab, Gyeongsangbuk Do 712701, South Korea
来源：
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2011年 / 11卷 / 02期
关键词：
ATRP; 1H; 1H-Perfluorooctyl Methacrylate; Poly (3-Hexylthiophene); Block Copolymer; BLOCK-COPOLYMERS; SOLAR-CELLS; REGIOREGULAR POLYTHIOPHENE; ELECTRICAL-CONDUCTIVITY; FACILE SYNTHESIS; POLYMERIZATION;
D O I：
10.1166/jnn.2011.3330
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This study reports the synthesis of regioregular poly(3-hexylthiophene)-b-poly(1H,1H-dihydro perfluorooctyl methacrylate) (P3HT-b-PFOMA) block copolymers by atom transfer radical polymerization of FOMA using P3HT macroinitiators. The P3HT macroinitiator was previously prepared by chemical modification of hydroxy terminated P3HT. The block copolymers were characterized by H-1-NMR, C-13-NMR, GPC, DSC, TGA and TEM. The block copolymers are able to self-assemble into phase separated micellar thin film morphology from chloroform.
引用
收藏
页码：1696 / 1700
页数：5
相关论文
共 22 条
  • [1] Nanoporous poly(3-alkylthiophene) thin films generated from block copolymer templates
    Boudouris, Bryan W.
    Frisbie, C. Daniel
    Hillmyer, Marc A.
    [J]. MACROMOLECULES, 2008, 41 (01) : 67 - 75
  • [2] Facile synthesis of well-defined block copolymers containing regioregular poly(3-hexyl thiophene) via anionic macroinitiation method and their self-assembly behavior
    Dai, Chi-An
    Yen, Wei-Che
    Lee, Yi-Huan
    Ho, Chun-Chi
    Su, Wei-Fang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (36) : 11036 - +
  • [3] Advances in polymer integrated optics
    Eldada, L
    Shacklette, LW
    [J]. IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS, 2000, 6 (01) : 54 - 68
  • [4] Multicomponent semiconducting polymer systems with low crystallization-induced percolation threshold
    Goffri, Shalom
    Mueller, Christian
    Stingelin-Stutzmann, Natalie
    Breiby, Dag W.
    Radano, Christopher P.
    Andreasen, Jens W.
    Thompson, Richard
    Janssen, Rene A. J.
    Nielsen, Martin M.
    Smith, Paul
    Sirringhaus, Henning
    [J]. NATURE MATERIALS, 2006, 5 (12) : 950 - 956
  • [5] Granstrom M., 1999, ELECTROOPTICAL POLYT
  • [6] Regioregular poly(3-alkylthiophene) conducting block copolymers
    Iovu, MC
    Jeffries-El, M
    Sheina, EE
    Cooper, JR
    McCullough, RD
    [J]. POLYMER, 2005, 46 (19) : 8582 - 8586
  • [7] Conducting regioregular polythiophene block copolymer nanofibrils synthesized by reversible addition fragmentation chain transfer polymerization (RAFT) and nitroxide mediated polymerization (NMP)
    Iovu, Mihaela C.
    Craley, C. Rockford
    Jeffries-EL, Malika
    Krankowski, Ashley B.
    Zhang, Rui
    Kowalewski, Tomasz
    McCullough, Richard D.
    [J]. MACROMOLECULES, 2007, 40 (14) : 4733 - 4735
  • [8] Facile synthesis of end-functionalized regioregular poly(3-alkylthiophene)s via modified Grignard metathesis reaction
    Jeffries-El, M
    Sauvé, G
    McCullough, RD
    [J]. MACROMOLECULES, 2005, 38 (25) : 10346 - 10352
  • [9] Katz H. E., 1999, OLIGO POLYTHIOPHENE
  • [10] Kim M.S., 2009, J Nanosci Nanotechnol, V9, P1
123