Lithium aluminate-based ceramic membranes as separators for lithium-ion batteries

被引：51
作者：
Raja, M. [1 ]
Sanjeev, Ganesh [2 ]
Kumar, T. Prem [1 ]
Stephan, A. Manuel [1 ]
机构：
[1] Cent Electrochem Res Inst, CSIR, Karaikkudi 630006, Tamil Nadu, India
[2] Mangalore Univ, Microtron Ctr, Mangalagangothri 574199, Karnataka, India
来源：
CERAMICS INTERNATIONAL | 2015年 / 41卷 / 02期
关键词：
Ionic conductivity; Ceramic membrane; Lithium aluminate; Dimensional stability; Lithium-ion battery; POLYMER ELECTROLYTES; COMPOSITE ELECTROLYTES; CYCLING PERFORMANCE;
D O I：
10.1016/j.ceramint.2014.10.142
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Lithium aluminate, (LiAlO2)-based porous ceramic membrane (PCM) was prepared with poly(vinylidene fluoride-hexafluoropropylene) as binder. Physical properties such as thermal stability, porosity and tortuosity of the pores were measured. Effective ionic conductivity and compatibility with lithium metal anode were also studied. The porous ceramic membrane was found to be dimensionally stable even at 135 degrees C. The cycling performance of 2032-type coin cell composed of Li/PCM/LiFePO4 was analyzed at different C-rates. A stable cycling was achieved at 0.1-C rate, which qualifies the membrane for lithium-ion battery applications. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码：3045 / 3050
页数：6
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