Two zinc-triazole-biphenyldicarboxylate coordination polymers affording a 3D 4-connected 2-fold interpenetrating diamond net and a 2D 6-connected hxl net

被引：4

作者：

Chen, Yanli ^{[1
]}

Fan, Yong ^{[1
]}

Zhang, Daojun ^{[1
]}

Huang, Liangliang ^{[1
]}

Jiang, Jinhua ^{[1
]}

Zhang, Ping ^{[1
]}

Xu, Jianing ^{[1
]}

机构：

[1] Jilin Univ, Dept Chem, Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 02期

关键词：

Secondary building units; Triazole; Diamond; hxl network; METAL-ORGANIC FRAMEWORKS; SECONDARY BUILDING UNITS; HYDROTHERMAL SYNTHESIS; TOPOLOGICAL NETWORK; CRYSTAL-STRUCTURE; CHEMISTRY; TRINUCLEAR; COMPLEXES; SYSTEM; LIGAND;

D O I：

10.1016/j.inoche.2010.11.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new zinc-triazole-biphenyldicarboxylate frameworks based on secondary building units (SBUs), namely, Zn-4(mu(4)-O)(trz)(2)(4,4'-bpdc)(2) (1) and Zn-2(trz)(2)(2,4'-bpdc) (2), [Htrz = 1,2,4-triazole, H(2)bpdc = biphenyldicarboxylate] have been synthesized by hydrothermal reactions and characterized by single-crystal X-ray diffraction analyses, X-ray power diffraction, elemental analyses, infrared absorption spectra, and thermogravimetric analyses. Compound 1 is a 2-fold interpenetrating diamond topology constructed from [Zn-4(mu(4)-O)(trz)(2)](4+) SBUs with tetrahedral [Zn-4(mu(4)-O)] core and two trz ligands. Compound 2 is a 2D 6-connected hxl network based on [Zn-2(trz)(2)](2+) SBUs. Additionally, these two compounds show emission properties at room temperature in the solid state. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.

引用

页码：343 / 346

页数：4

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