The preparation, characterization and x-ray structural analysis of tetrakis[1,3-dimethyl-2(3H)-imidazoleselone]cadmium(II) hexafluorophosphate

被引：15

作者：

Williams, Daniel J. ^{[1
]}

McKinney, Bradley J.

Baker, Ben

Gwaltney, Kevin P.

VanDerveer, Donald

机构：

[1] Kennesaw State Univ, Dept Chem & Biochem, Kennesaw, GA 30144 USA

[2] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2007年 / 37卷 / 10期

关键词：

X-ray crystallography; cadmium complex; dimethylimidazoleselone; homoleptic complex;

D O I：

10.1007/s10870-007-9233-6

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A new compound, [ Cd(dmise)(4)][ PF6](2), has been synthesized and characterized via standard solid and solution state methods including single crystal X-ray crystallography ( dmise = 1,3-dimethyl-2( 3H)-imidazoleselone). The title compounds crystallizes in orthorhombic space group P bcn with a = 12.783( 3), b = 22.206( 4), c = 13.153( 3) angstrom, V = 3733.8( 13) angstrom(3), Z = 4. The complex is a high melting, yellow water soluble 2: 1 electrolyte solid that state has a flattened tetrahedral CdSe4 coordination geometry. To date this is the only structural study reported for a homoleptic selenourea complex of cadmium.

引用

页码：691 / 694

页数：4

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