The preparation, characterization and x-ray structural analysis of tetrakis[1,3-dimethyl-2(3H)-imidazoleselone]cadmium(II) hexafluorophosphate

被引：15
|
作者：
Williams, Daniel J. [1 ]
McKinney, Bradley J.
Baker, Ben
Gwaltney, Kevin P.
VanDerveer, Donald
机构：
[1] Kennesaw State Univ, Dept Chem & Biochem, Kennesaw, GA 30144 USA
[2] Clemson Univ, Dept Chem, Clemson, SC 29634 USA
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2007年 / 37卷 / 10期
关键词：
X-ray crystallography; cadmium complex; dimethylimidazoleselone; homoleptic complex;
D O I：
10.1007/s10870-007-9233-6
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new compound, [ Cd(dmise)(4)][ PF6](2), has been synthesized and characterized via standard solid and solution state methods including single crystal X-ray crystallography ( dmise = 1,3-dimethyl-2( 3H)-imidazoleselone). The title compounds crystallizes in orthorhombic space group P bcn with a = 12.783( 3), b = 22.206( 4), c = 13.153( 3) angstrom, V = 3733.8( 13) angstrom(3), Z = 4. The complex is a high melting, yellow water soluble 2: 1 electrolyte solid that state has a flattened tetrahedral CdSe4 coordination geometry. To date this is the only structural study reported for a homoleptic selenourea complex of cadmium.
引用
收藏
页码：691 / 694
页数：4
相关论文
共 50 条
  • [11] Dichlorobis [1,3-dimethyl-2(3H)-imidazoloselone]zinc(II):: a potential zinc selenide synthon
    Williams, DJ
    White, KM
    VanDerveer, D
    Wilkinson, AP
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (02) : 124 - 126
  • [12] ADDUCTS OF GROUP-5A TRIHALIDES WITH 1,3-DIMETHYL-2(3H)-IMIDAZOLETHIONE
    WILLIAMS, DJ
    VIEHBECK, A
    INORGANIC CHEMISTRY, 1979, 18 (07) : 1823 - 1825
  • [13] SYNTHESIS, PROPERTIES, AND STRUCTURE OF 1,3-DIMETHYL-2(3H)-IMIDAZOLETHIONE HYDROGEN BROMIDE
    WILLIAMS, DJ
    RAMIREZ, G
    VANDERVEER, D
    JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1986, 16 (03): : 309 - 332
  • [14] PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF HEXAKIS(1-METHYLIMIDAZOLINE-2(3H)-THIONE)TETRAKIS(NITRATO)DILEAD(II)
    BRISTOW, S
    HARRISON, JA
    FARRUGIA, LJ
    POLYHEDRON, 1987, 6 (12) : 2177 - 2180
  • [15] Structural characterization of tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate
    Mahmood, R.
    Hussain, S. G.
    Isab, A. A.
    Fettouhi, M.
    Fazal, A.
    Ahmad, S.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 56 (03) : 463 - 467
  • [16] Structural characterization of tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate
    R. Mahmood
    S. G. Hussain
    A. A. Isab
    M. Fettouhi
    A. Fazal
    S. Ahmad
    Journal of Structural Chemistry, 2015, 56 : 463 - 467
  • [17] CRYSTAL AND MOLECULAR-STRUCTURE OF TRICHLORO[1,3-DIMETHYL-2(3H)-IMIDAZOLETHIONE]ARSENIC(III)
    WILLIAMS, DJ
    QUICKSALL, CO
    WYNNE, KJ
    INORGANIC CHEMISTRY, 1978, 17 (08) : 2071 - 2073
  • [18] The synthesis, characterization, and crystal structures of two new complexes of 1,3-dimethyl-2(3H)-imidazolethione with indium trihalides.
    Williams, DJ
    Morson, PA
    Pennington, WT
    VanDerveer, D
    Kruger, JS
    Kawai, NT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 225 - INOR
  • [19] CRYSTAL AND MOLECULAR-STRUCTURE OF TRICHLORO[1,3-DIMETHYL-2(3H)-IMIDAZOLETHIONE]ANTIMONY-(III)
    RUBIN, B
    HELDRICH, FJ
    DEAN, WK
    WILLIAMS, DJ
    VIEHBECK, A
    INORGANIC CHEMISTRY, 1981, 20 (12) : 4434 - 4437
  • [20] Synthesis and Characterization of 1:2 Complex of Mercury(II) Chloride with 1,3-Dimethyl-1H-Imidazole-2(3H)-Thione
    Ramesh Karri
    Mainak Banerjee
    Rakesh Rai
    Gouriprasanna Roy
    Proceedings of the National Academy of Sciences, India Section A: Physical Sciences, 2016, 86 : 611 - 617
12345