Piperazinium aquabis(oxalato) oxidovanadate(IV) dihydrate

被引：10
作者：
Aghabozorg, Hossein
Motyeian, Elham
Aghajani, Zahra
Ghadermazi, Mohammad
Gharamaleki, Jafar Attar
机构：
[1] Teacher Training Univ, Dept Chem, Tehran 15614, Iran
[2] Islamic Azad Univ, Dept Chem, Qom Branch, Tehran, Iran
[3] Kurdistan Univ, Fac Sci, Dept Chem, Sanandaj, Iran
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807023616
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, (C(4)H(12)N(2))[V(C(2)O(4))(2)O(H(2)O)] center dot 2H(2)O, has been obtained by the reaction of vanadium( III) chloride with piperazinediium oxalate in aqueous solution. It shows distorted octahedral geometry [ V=O =1.6010 ( 12) angstrom and V - O = 1.9932 ( 12) - 2.2176 ( 12) A]]. The structure exhibits intermolecular N - H center dot center dot center dot O and C - H center dot center dot center dot O hydrogen bonds. The uncoordinated water molecules contribute to the formation of the supramolecular structure via O - H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：M1754 / U1527
页数：12
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