Application of sputtered TiO2 thin films as HRT buffer layer for high efficiency CdS/CdTe solar cells

被引:14
作者
Hernandez-Rodriguez, E. [1 ]
Rejon, V. [2 ]
Mis-Fernandez, R. [2 ]
Pena, J. L. [2 ]
机构
[1] Univ Guanajuato, DICIS, Dept Engn, Carretera Salamanca Valle Santiago Km 3-5 1-8, Salamanca 36885, Gto, Mexico
[2] IPN, CINVESTAV, Dept Appl Phys, Merida 97310, Yucatan, Mexico
关键词
TiO2; Thin films; Solar cell; HRT; Buffer layer; PERFORMANCE; STABILITY;
D O I
10.1016/j.solener.2016.02.047
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this work titanium dioxide (TiO2) thin films were developed for application as high resistance transparent (HRT) buffer layer (BL) in high efficiency CdS/CdTe solar cells. The TiO2 HRT-BLs where deposited by the reactive RF-Sputtering technique. The solar cells had the superstrate configuration and the CdTe absorber was deposited by conventional Close Space Sublimation (CSS). Solar cells with optimized TiO2 HRT-BL had improved photoresponse in the blue wavelength region. A 15 nm TiO2 film avoids migration of chemical species from the ITO front contact toward the CdS/CdTe photovoltaic heterojunction. Solar cells with the TiO2 HRT-BL have improved temperature coefficient of efficiency. A photoconversion efficiency of 12.0% was obtained by employing a 15 nm TiO2 HRT-BL. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:64 / 72
页数:9
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