Periodate oxidation of polysaccharides for modification of chemical and physical properties

被引：274
作者：
Kristiansen, Kare A. [1 ]
Potthast, Antje [2 ]
Christensen, Bjorn E. [1 ]
机构：
[1] Norwegian Univ Sci & Technol NTNU, Dept Biotechnol, NOBIPOL, NO-7491 Trondheim, Norway
[2] Univ Nat Resources & Appl Life Sci BOKU, Dept Chem, A-1190 Vienna, Austria
来源：
CARBOHYDRATE RESEARCH | 2010年 / 345卷 / 10期
关键词：
Periodate oxidation; Dialdehyde; Alginate; Chitosan; Scleroglucan; Cellulose; DEACETYLATED CHITINS CHITOSANS; ANION-EXCHANGE CHROMATOGRAPHY; FIELD NMR-SPECTROSCOPY; AQUEOUS-SOLUTION; CHAIN STIFFNESS; CONFORMATIONAL TRANSITIONS; THERMAL-DECOMPOSITION; DIALDEHYDE CELLULOSE; INTRINSIC-VISCOSITY; METHYL CELLULOSE;
D O I：
10.1016/j.carres.2010.02.011
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A limited degree (typically 1-20%) of periodate oxidation of polysaccharides may give rise to derivatives with entirely altered chemical and physical properties. Notably, the ring opening caused by periodate leads to the formation of highly flexible 'hinges' in otherwise rather semiflexible or rigid structures. This review highlights selected examples with the main focus on periodate oxidation of alginates, chitosans, hyaluronan, scleroglucan/schizophyllan, and cellulose. (C) 2010 Elsevier Ltd. All rights reserved.
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页码：1264 / 1271
页数：8
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