A new polyoxometalate-based 3d-4f heterometallic aggregate: a model for the design and synthesis of new heterometallic clusters

被引:99
作者
Chen, Weilin [1 ]
Li, Yangguang [1 ]
Wang, Yonghui [1 ]
Wang, Enbo [1 ]
Zhang, Zhiming [1 ]
机构
[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
关键词
D O I
10.1039/b717419e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new polytungstoarsenate-based 3d-4f heterometallic aggregate has been synthesized, consisting of three {alpha-(AsWO38)-O-10} fragments bridged by three {Fe-(mu(3)-O)(3)-Ce} heterometallic clusters.
引用
收藏
页码:865 / 867
页数:3
相关论文
共 47 条
[11]   Polyoxometalate- supported Y- and YbIII-hydroxo/oxo clusters from carbonate-assisted hydrolysis [J].
Fang, XK ;
Anderson, TM ;
Benelli, C ;
Hill, CL .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (02) :712-718
[12]   Alkali-metal-controlled self-assembly of crown-shaped ring complexes of lanthanide/[α-AsW9O33]9-: [K⊂{Eu(H2O)2(α-AsW9O33)}6]35- and [Cs⊂{Eu(H2O)2(α-AsW9O33)}4]23- [J].
Fukaya, K ;
Yamase, T .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (06) :654-658
[13]   Coordination chemistry of the hexavacant tungstophosphate [H2P2W12O48]12- with FeIII ions:: Towards original structures of increasing size and complexity [J].
Godin, B ;
Chen, YG ;
Vaissermann, J ;
Ruhlmann, L ;
Verdaguer, M ;
Gouzerh, P .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (20) :3072-3075
[14]   Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices [J].
Long, De-Liang ;
Burkholder, Eric ;
Cronin, Leroy .
CHEMICAL SOCIETY REVIEWS, 2007, 36 (01) :105-121
[15]   Reactions of a {Mo16}-type polyoxometalate cluster with electrophiles:: a synthetic, theoretical and magnetic investigation [J].
Long, DL ;
Kögerler, P ;
Farrugia, LJ ;
Cronin, L .
DALTON TRANSACTIONS, 2005, (08) :1372-1380
[16]   A high-nuclearity "Celtic-Ring" isopolyoxotungstate, [H12W36O120] that captures trace potassium ions [J].
Long, DL ;
Abbas, H ;
Kögerler, P ;
Cronin, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (43) :13880-13881
[17]   Restraining symmetry in the formation of small polyoxomolybdates:: Building blocks of unprecedented topology resulting from "shrink-wrapping" [H2Mo16O52]10--type clusters [J].
Long, DL ;
Kögerler, P ;
Farrugia, LJ ;
Cronin, L .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (35) :4180-4183
[18]   The wheel-shaped Cu20 tungstophosphate [Cu20Cl(OH)24(H2O)12(P8W48O184)]25- ion [J].
Mal, SS ;
Kortz, U .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (24) :3777-3780
[19]   A bell-shaped Mn11Gd2 single-molecule magnet [J].
Mereacre, Valeriu M. ;
Ako, Ayuk M. ;
Clerac, Rodolphe ;
Wernsdorfer, Wolfgang ;
Filoti, George ;
Bartolome, Juan ;
Anson, Christopher E. ;
Powell, Annie K. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (30) :9248-+
[20]   Functionalization of polyoxometalates by a negatively charged bridging ligand:: The dimeric [(SiW11O39Ln)2(μ-CH3COO)2]12- (Ln = GdIII, YbIII) complexes [J].
Mialane, P ;
Dolbecq, A ;
Rivière, E ;
Marrot, J ;
Sécheresse, F .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (01) :33-36