A new polyoxometalate-based 3d-4f heterometallic aggregate: a model for the design and synthesis of new heterometallic clusters

被引：99

作者：

Chen, Weilin ^{[1
]}

Li, Yangguang ^{[1
]}

Wang, Yonghui ^{[1
]}

Wang, Enbo ^{[1
]}

Zhang, Zhiming ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China

来源：

DALTON TRANSACTIONS | 2008年 / 8卷 / 07期

关键词：

D O I：

10.1039/b717419e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new polytungstoarsenate-based 3d-4f heterometallic aggregate has been synthesized, consisting of three {alpha-(AsWO38)-O-10} fragments bridged by three {Fe-(mu(3)-O)(3)-Ce} heterometallic clusters.

引用

页码：865 / 867

页数：3

共 47 条

[1] Redox behavior of cerium in heteropolyoxotungstate complexes [J].

Antonio, MR ;

Soderholm, L ;

Williams, CW ;

Ullah, N ;

Francesconi, LC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (21) :3825-3830

[2] Topotactic redox reactions of copper(II) and iron(III) salts within VOx nanotubes [J].

Azambre, B ;

Hudson, MJ ;

Heintz, O .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (02) :385-393

[3] The tungstogermanate [Ce20Ge10W100O376(OH)4(H2O)30]56-:: A polyoxometalate containing 20 Cerium(III) atoms [J].

Bassil, Bassem S. ;

Dickman, Michael H. ;

Roemer, Isabella ;

von der Kammer, Bernd ;

Kortz, Ulrich .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (32) :6192-6195

[4] Structure, electrochemistry, and magnetism of the iron(III)-substituted Keggin dimer, [Fe6(OH)3(A-α-GeW9O34(OH)3)2]11- [J].

Bi, LH ;

Kortz, U ;

Nellutla, S ;

Stowe, AC ;

van Tol, J ;

Dalal, NS ;

Keita, B ;

Nadjo, L .

INORGANIC CHEMISTRY, 2005, 44 (04) :896-903

[5]

BOTAR B, 2007, CHEM COMMUN, V13, P8739

[6] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[7] Building block approach to nanostructures: step-by-step assembly of large lanthanide-containing polytungstoarsenate aggregates [J].

Chen, Weilin ;

Li, Yangguang ;

Wang, Yonghui ;

Wang, Enbo ;

Su, Zhongmin .

DALTON TRANSACTIONS, 2007, (38) :4293-4301

[8] An inorganic aggregate based on a sandwich-type polyoxometalate with lanthanide and potassium cations: From ID chiral ladder-like chains to a 3D open framework [J].

Chen, Weilin ;

Li, Yangguang ;

Wang, Yonghui ;

Wang, Enbo .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (15) :2216-2220

[9] Magnetic clusters from polyoxometalate complexes [J].

Clemente-Juan, JM ;

Coronado, E .

COORDINATION CHEMISTRY REVIEWS, 1999, 193-5 :361-394

[10] New inorganic-organic hybrid materials based on polyoxovanadates:: [Morp]6[VO4⊂CV14O32(OH)6] • 2H2O, [Morp]VO3, [HMTA-CH3]4[H2V10O28] • 5H2O, and [HMTA-H][HMTA-CH2OH]2[H5V10O28] • 6H2O [J].

Duraisamy, T ;

Ojha, N ;

Ramanan, A ;

Vittal, JJ .

CHEMISTRY OF MATERIALS, 1999, 11 (09) :2339-2349

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