Photo-Fenton reaction and H2O2 enhanced photocatalytic activity of α-Fe2O3 nanoparticles obtained by a simple decomposition route

被引：61

作者：

Liu, Jinsong ^{[1
,2
]}

Wang, Bijun ^{[1
]}

Li, Ziquan ^{[1
,3
]}

Wu, Zhengying ^{[4
]}

Zhu, Kongjun ^{[2
]}

Zhuang, Jiajia ^{[1
]}

Xi, Qingyang ^{[1
]}

Hou, Yindi ^{[1
]}

Chen, Jiankang ^{[1
]}

Cong, Mengqi ^{[1
]}

Li, Jun ^{[2
]}

Qian, Guoming ^{[2
]}

Lin, Zixia ^{[5
]}

机构：

[1] Nanjing Univ Aeronaut & Astronaut, Dept Mat Sci & Technol, Nanjing 211106, Jiangsu, Peoples R China

[2] Nanjing Univ Aeronaut & Astronaut, State Key Lab Mech & Control Mech Struct, Nanjing 210016, Jiangsu, Peoples R China

[3] Nanjing Univ Posts & Telecommun, Inst Adv Mat, Nanjing 210003, Jiangsu, Peoples R China

[4] Suzhou Univ Sci & Technol, Lab Environm Funct Mat, Suzhou 215009, Peoples R China

[5] Yangzhou Univ, Testing Ctr, Yangzhou 225009, Jiangsu, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2019年 / 771卷

关键词：

alpha-Fe2O3; nanoparticles; Band gap; Photocatalytic degradation; Photo-Fenton reaction; SOLID-STATE SYNTHESIS; HYDROTHERMAL SYNTHESIS; ELECTRON-TRANSFER; NANOCRYSTALS; DEGRADATION; MECHANISM; GROWTH; NANOSTRUCTURES; DISSOLUTION; PERFORMANCE;

D O I：

10.1016/j.jallcom.2018.08.305

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

alpha-Fe2O3 nanoparticles with different sizes were successfully synthesized by a simple SDS-assisted grinding reaction and subsequent heating treatment process. Effects of calcination temperatures on crystal structure, optical and photocatalytic properties of the products were investigated by TG-DSC, FTIR, XRD, TEM, HRTEM, and UV-Vis techniques. Results showed that growth of the alpha-Fe2O3 nanoparticles was very slow, and the average crystallite size gradually increased with increasing calcination temperatures. Optical measure and calculation showed that there is an increasing trend for the band gap with increase of calcination temperature. The alpha-Fe2O3 nanoparticles obtained at 500 degrees C revealed higher photocatalytic degradation efficiency for MB than the other samples, attributing to the optimal value between transiting electrons and recombination of electron-hole pairs. Radical scavengers experiments implied that center dot OH and e(-) played important roles in the photocatalytic process. The photodegradation time was greatly shortened, and the photocatalytic efficiency was further enhanced and raised to over 90% after adding H2O2, which is due to generation of a large number of the highly oxidative center dot OH by photo-Fenton reaction. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：398 / 405

页数：8

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