{μ-6,6′-Dimethoxy-2,2-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)dysprosium(III) methanol monosolvate

被引：1

作者：

Xu, Lili ^{[1
]}

Li, Hong-Feng ^{[1
]}

Chen, Peng ^{[1
]}

Yan, Peng-Fei ^{[1
]}

机构：

[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

基金：

中国国家自然科学基金;

关键词：

MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; COMPLEX;

D O I：

10.1107/S1600536811005253

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title heterodinuclear salen-type complex, [CuDy(C19H20N2O4)(NO3)(3)]center dot CH3OH, the copper(II) ion is tetracoordinated by two imino N atoms [Cu-N = 1.961 (4) and 1.968 (4) angstrom] and two phenolate O atoms [Cu-O = 1.931 (3) and 1.938 (3) angstrom] in a planar geometry. The tencoordinate Dy-III ion is ligated by six O atoms of three nitrate groups and four O atoms from the ligand [Dy-O = 2.368 (3)- 2.601 (3) angstrom]. In the crystal, complex molecules and solvent molecules are linked by intermolecular O-H center dot center dot center dot O hydrogen bonds.

引用

页码：M367 / U809

页数：12

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