Densities, Speeds of Sound, Excess Molar Volumes, and Excess Isentropic Compressibilities at T = (298.15 and 308.15) K for Methyl Methacrylate+1-Alkanols (1-Butanol, 1-Pentanol, and 1-Heptanol) plus Cyclohexane, plus Benzene, plus Toluene, plus p-Xylene, and plus Ethylbenzene

被引:31
作者
Sastry, Nandhibatla V. [1 ]
Patel, Sunil R. [1 ]
Soni, Saurabh S. [1 ]
机构
[1] Sardar Patel Univ, Dept Chem, Vallabh Vidyanagar 388120, Gujarat, India
关键词
BINARY-MIXTURES; O-XYLENE; THERMODYNAMIC PROPERTIES; HEAT-CAPACITIES; N-HEXANE; RELATIVE PERMITTIVITIES; REFRACTIVE-INDEX; VISCOSITIES; POLARIZATIONS; TEMPERATURES;
D O I
10.1021/je100652b
中图分类号
O414.1 [热力学];
学科分类号
摘要
The densities and speeds of sound for ternary mixtures of methyl methacrylate (MMA) + 1-alkanols (1-butanol, 1-pentanol, 1-heptanol) + aromatic organic solvents (benzene, toluene, p-xylene, and ethylbenzene) or + cyclohexane have been measured at T/K = (298.15 and 308.15). Excess molar volumes and excess isentropic compressibilities were calculated across the mole fraction range, and the same were compared with the values calculated using similar data for the binary pairs through Redlich-Kister (RK), Tsao and Smith (TS), and Kohler (K) equations. As compared to others, the RK equation predicted the excess molar volumes and excess isentropic compressibilities adequately.
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页码:142 / 152
页数:11
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