Ultrahigh sensitive and selective room-temperature carbon monoxide gas sensor based on polypyrrole/titanium dioxide nanocomposite

被引:37
作者
Farea, Maamon A. [1 ,2 ]
Bhanuse, Gita B. [1 ]
Mohammed, Hamed Y. [1 ,3 ]
Farea, Mohammed O. [2 ]
Sallam, Mohyeddine [3 ]
Shirsat, Sumedh M. [4 ]
Tsai, Meng-Lin [4 ]
Shirsat, Mahendra D. [1 ]
机构
[1] Dr Babasaheb Ambedkar Marathwada Univ, RUSA Ctr Adv Sensor Technol, Dept Phys, Aurangabad 431004, MS, India
[2] Ibb Univ, Dept Phys, Ibb, Yemen
[3] Taiz Univ, Dept Phys, Taizi, Yemen
[4] Natl Taiwan Univ Sci & Technol, Dept Mat Sci & Engn, Taipei 10607, Taiwan
关键词
Carbon monoxide; Polypyrrole; Titanium dioxide; Ultrahigh sensitive; Gas sensor; SENSING PROPERTIES; HIGH RESPONSE; PERFORMANCE; FABRICATION; PARTICLES;
D O I
10.1016/j.jallcom.2022.165397
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this article, an ultrahigh sensitive and selective carbon monoxide (CO) gas sensor was developed and studied at room temperature utilizing the PPy/TiO2 nanocomposite. The gas sensors were fabricated through drop-casting the PPy/TiO2 nanocomposites on the surface of interdigitated electrodes. All the nanocomposites have been synthesized via a chemical oxidation method. Contrary to the pure PPy sensor, PPy/TiO2 sensor exhibited 4-fold enhanced sensitivity. Our sensor showed a superior response of order 93 at 270 ppm of carbon monoxide with high selectivity over the other interference gases. Additionally, our sensor exhibited a quick response time and a short recovery time of 36 s and 38 s, long-term stability, excellent repeatability, and satisfactory reproducibility. Accordingly, experimental findings proved that incorporating TiO2 into the PPy plays an influential role in enhancing the gas sensor performance. In this work, based on the outstanding CO sensing performance, the PPy/TiO2 based sensor might be considered a promising candidate for real-time gas sensor applications. (C) 2022 Published by Elsevier B.V.
引用
收藏
页数:11
相关论文
共 49 条
[1]   Influence of green synthesized gold nanoparticles on the structural, optical, electrical and dielectric properties of (PVP/SA) blend [J].
Abdelghany, A. M. ;
Oraby, A. H. ;
Farea, M. O. .
PHYSICA B-CONDENSED MATTER, 2019, 560 :162-173
[2]   The development of gas sensor for carbon monoxide monitoring using nanostructure of Nb-TiO2 [J].
Anukunprasert, T ;
Saiwan, C ;
Traversa, E .
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2005, 6 (3-4) :359-363
[3]   Synthesis and characterization of soluble polypyrrole-poly(ε-caprolactone) polymer blends with improved electrical conductivities [J].
Basavaraja, C. ;
Kim, Won Jung ;
Kim, Dae Gun ;
Huh, Do Sung .
MATERIALS CHEMISTRY AND PHYSICS, 2011, 129 (03) :787-793
[4]   Fabrication and performance of polypyrrole (Ppy)/TiO2 heterojunction for room temperature operated LPG sensor [J].
Bulakhe, R. N. ;
Patil, S. V. ;
Deshmukh, P. R. ;
Shinde, N. M. ;
Lokhande, C. D. .
SENSORS AND ACTUATORS B-CHEMICAL, 2013, 181 :417-423
[5]   LaNiTiO3-SE-based stabilized zirconium oxide mixed potentiometric SO2 gas sensor [J].
Cao, Zongqiang ;
Gao, Qiong ;
Zhou, Mincong ;
Li, Xu ;
Wang, Qingji .
CERAMICS INTERNATIONAL, 2022, 48 (07) :9269-9276
[6]   TiO2/polypyrrole nanocomposites photoactive under visible light synthesized by heterophase polymerization in the presence of different surfactants [J].
Castillo-Reyes, Blanca E. ;
Ovando-Medina, Victor M. ;
Gonzalez-Ortega, Omar ;
Alonso-Davila, Pedro A. ;
Juarez-Ramirez, Isaias ;
Martinez-Gutierrez, Hugo ;
Marquez-Herrera, A. .
RESEARCH ON CHEMICAL INTERMEDIATES, 2015, 41 (11) :8211-8231
[7]   Synthesis and Characterization of Polypyrrole-Coated Anthracene Microparticles: A New Synthetic Mimic for Polyaromatic Hydrocarbon-Based Cosmic Dust [J].
Chan, Derek H. ;
Millet, Arthur ;
Fisher, Callum R. ;
Price, Mark C. ;
Burchell, Mark J. ;
Armes, Steven P. .
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (02) :3175-3185
[8]  
Chekuri Radha Devi, 2017, South African Journal of Chemical Engineering, V24, P183, DOI 10.1016/j.sajce.2017.10.001
[9]   High sensitive room temperature NO2 gas sensor based on the avalanche breakdown induced by Schottky junction in TiO2-Sn3O4 nanoheterojunctions [J].
Chen, Duo ;
Yu, Wencheng ;
Wei, Lin ;
Ni, Jiasheng ;
Li, Hui ;
Chen, Yanxue ;
Tian, Yufeng ;
Yan, Shishen ;
Mei, Liangmo ;
Jiao, Jun .
JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 912
[10]   Identification and discrimination of polycyclic aromatic hydrocarbons using Raman spectroscopy [J].
Cloutis, Edward ;
Szymanski, Paul ;
Applin, Daniel ;
Goltz, Douglas .
ICARUS, 2016, 274 :211-230