Recent advances in asymmetric phosphine oxide catalysis

被引：21

作者：

Kotani, Shunsuke ^{[1
]}

Nakajima, Makoto ^{[1
]}

机构：

[1] Kumamoto Univ, Grad Sch Pharmaceut Sci, Chuo Ku, 5-1 Oe Honmachi, Kumamoto 8620973, Japan

来源：

TETRAHEDRON LETTERS | 2020年 / 61卷 / 04期

基金：

日本学术振兴会;

关键词：

Aldol reaction; Enantioselectivity; Halocyclization; Phosphine oxide; Sequential catalysis; ABRAMOV-TYPE PHOSPHONYLATION; PYRIDINE N-OXIDES; BIHETEROAROMATIC DIPHOSPHINE OXIDES; ENANTIOSELECTIVE ALDOL REACTIONS; LEWIS-BASE ACTIVATION; MESO-EPOXIDES; STEREOSELECTIVE-SYNTHESIS; TRICHLOROSILYL TRIFLATE; AZIRIDINYL PHOSPHONATE; SILICON TETRACHLORIDE;

D O I：

10.1016/j.tetlet.2019.151421

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phosphine oxides are versatile catalysts in organic synthesis and mediate a broad range of transformations. In this digest, we review the recent developments in phosphine oxide-catalyzed asymmetric reactions. The enantioselective double aldol reactions, enantioselective aldol reaction of carboxylic acids, and enantioselective halocyclizations are discussed. These novel phosphine oxide-catalyzed processes are vital for the stereoselective synthesis and functionalization of useful organic molecules and intermediates. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页数：8

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