Scalable and Controllable Synthesis of Interface-Engineered Nanoporous Host for Dendrite-Free and High Rate Zinc Metal Batteries

被引：197
作者：
An, Yongling [1 ]
Tian, Yuan [1 ]
Xiong, Shenglin [2 ]
Feng, Jinkui [1 ]
Qian, Yitai [3 ]
机构：
[1] Shandong Univ, SDU & Rice Joint Ctr Carbon Nanomat, Sch Mat Sci & Engn, Key Lab Liquid Solid Struct Evolut & Proc Mat,Min, Jinan 250061, Peoples R China
[2] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
[3] Univ Sci & Technol China, Dept Chem, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
来源：
ACS NANO | 2021年 / 15卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Zn metal batteries; MXene; dendrite free; zincophilic layer; dealloying; LONG-LIFE; ELECTROLYTE; ANODE;
D O I：
10.1021/acsnano.1c02928
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rechargeable zinc (Zn)-ion batteries are regarded as highly prospective candidates for next-generation renewable and safe energy storage systems. However, the uncontrolled dendrite growth of the Zn anode impedes their practical application. Here, a scalable and controllable approach is developed for converting commercial titanium (Ti) foil to 3D porous Ti, which retains good resistance to corrosion, high electrical conductivity, and excellent mechanical properties. Benefiting from a spontaneous ultrathin zincophilic titanium dioxide (TiO2) interfacial layer and continuous 3D structure, the 3D porous Ti can act as an effective host to achieve a 3D Ti/Zn metal anode. By ensuring homogeneous nucleation, uniform current distribution, and volume change accommodation, the dendritic growth of 3D Ti/Zn metal anode is effectively inhibited with stable Zn plating/stripping up to 2000 h with low polarization. When conjugated with a 3D sulfur-doped Ti3C2Tx MXene@MnO2 nanotube cathode, a high rate and stable Zn cell is achieved with 95.46% capacity retention after 500 cycles at a high rate of 5 A g(-1). This work may also be interesting for researches in porous metals and other battery systems.
引用
收藏
页码：11828 / 11842
页数：15
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共 75 条
[1]   Recent advances and perspectives of 2D silicon: Synthesis and application for energy storage and conversion [J].
An, Yongling ;
Tian, Yuan ;
Wei, Chuanliang ;
Zhang, Yuchan ;
Xiong, Shenglin ;
Feng, Jinkui ;
Qian, Yitai .
ENERGY STORAGE MATERIALS, 2020, 32 :115-150
[2]   Stable Aqueous Anode-Free Zinc Batteries Enabled by Interfacial Engineering [J].
An, Yongling ;
Tian, Yuan ;
Zhang, Kai ;
Liu, Yongpeng ;
Liu, Chengkai ;
Xiong, Shenglin ;
Feng, Jinkui ;
Qian, Yitai .
ADVANCED FUNCTIONAL MATERIALS, 2021, 31 (26)
[3]   Dealloying: An effective method for scalable fabrication of 0D, 1D, 2D, 3D materials and its application in energy storage [J].
An, Yongling ;
Tian, Yuan ;
Wei, Chuanliang ;
Tao, Yuan ;
Xi, Baojuan ;
Xiong, Shenglin ;
Feng, Jinkui ;
Qian, Yitai .
NANO TODAY, 2021, 37
[4]   Two-Dimensional Silicon/Carbon from Commercial Alloy and CO2 for Lithium Storage and Flexible Ti3C2Tx MXene-Based Lithium-Metal Batteries [J].
An, Yongling ;
Tian, Yuan ;
Zhang, Yuchan ;
Wei, Chuanliang ;
Tan, Liwen ;
Zhang, Chenghui ;
Cui, Naxin ;
Xiong, Shenglin ;
Feng, Jinkui ;
Qian, Yitai .
ACS NANO, 2020, 14 (12) :17574-17588
[5]   Heteroatom-doped 3D porous carbon architectures for highly stable aqueous zinc metal batteries and non-aqueous lithium metal batteries [J].
An, Yongling ;
Tian, Yuan ;
Li, Yuan ;
Wei, Chuanliang ;
Tao, Yuan ;
Liu, Yongpeng ;
Xi, Baojuan ;
Xiong, Shenglin ;
Feng, Jinkui ;
Qian, Yitai .
CHEMICAL ENGINEERING JOURNAL, 2020, 400
[6]   Porosity- and Graphitization-Controlled Fabrication of Nanoporous Silicon@Carbon for Lithium Storage and Its Conjugation with MXene for Lithium-Metal Anode [J].
An, Yongling ;
Tian, Yuan ;
Wei, Hao ;
Xi, Baojuan ;
Xiong, Shenglin ;
Feng, Jinkui ;
Qian, Yitai .
ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (09)
[7]   Scalable and Physical Synthesis of 2D Silicon from Bulk Layered Alloy for Lithium-Ion Batteries and Lithium Metal Batteries [J].
An, Yongling ;
Tian, Yuan ;
Wei, Chuanliang ;
Jiang, Huiyu ;
Xi, Baojuan ;
Xiong, Shenglin ;
Feng, Jinkui ;
Qian, Yitai .
ACS NANO, 2019, 13 (12) :13690-13701
[8]   Micron-Sized Nanoporous Antimony with Tunable Porosity for High-Performance Potassium-Ion Batteries [J].
An, Yongling ;
Tian, Yuan ;
Ci, Lijie ;
Xiong, Shenglin ;
Feng, Jinkui ;
Qian, Yitai .
ACS NANO, 2018, 12 (12) :12932-12940
[9]   Vacuum distillation derived 3D porous current collector for stable lithium-metal batteries [J].
An, Yongling ;
Fei, Huifang ;
Zeng, Guifang ;
Xu, Xiaoyan ;
Ci, Lijie ;
Xi, Baojuan ;
Xiong, Shenglin ;
Feng, Jinkui ;
Qian, Yitai .
NANO ENERGY, 2018, 47 :503-511
[10]   Green, Scalable, and Controllable Fabrication of Nanoporous Silicon from Commercial Alloy Precursors for High-Energy Lithium-Ion Batteries [J].
An, Yongling ;
Fei, Huifang ;
Zeng, Guifang ;
Ci, Lijie ;
Xiong, Shenglin ;
Feng, Jinkui ;
Qian, Yitai .
ACS NANO, 2018, 12 (05) :4993-5002
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