Single-Chain Polymeric Nanoparticles by Stepwise Folding

被引：189
作者：
Mes, Tristan [1 ]
van der Weegen, Rob [1 ]
Palmans, Anja R. A. [1 ]
Meijer, E. W. [1 ]
机构：
[1] Eindhoven Univ Technol, Inst Complex Mol Syst, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 22期
关键词：
circular dichroism; folding; nanoparticles; photodeprotection; supramolecular chemistry; INTRAMOLECULAR CROSS-LINKING; STAR POLYMERS; RADICAL POLYMERIZATION; BLOCK-COPOLYMERS; TERMINAL ALKYNES; DILUTE-SOLUTION; SOLID-STATE; BENZENE-1,3,5-TRICARBOXAMIDES; CATALYSTS; COLLAPSE;
D O I：
10.1002/anie.201100104
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Light-induced self-assembly leads to the folding of synthetic random-coil polymers into highly stable single-chain polymeric chiral nanoparticles (see picture; green: side chains, blue: phenyl rings, red: nitrophenyl leaving groups). The folding of the polymer was aided by heating and cooling steps. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：5085 / 5089
页数：5
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