Activity Coefficients at Infinite Dilution in Methylimidazolium Nitrate Ionic Liquids

被引:27
作者
Foco, Gloria [1 ]
Dolores Bermejo, M. [2 ]
Kotlewska, Aleksandra J. [3 ]
van Rantwijk, Fred [3 ]
Peters, Cor J. [4 ,5 ]
Bottini, Susana B. [1 ]
机构
[1] UNS CONICET, PLAPIQUI, RA-8000 Bahia Blanca, Buenos Aires, Argentina
[2] Univ Valladolid, High Pressure Proc Grp, Dept Chem Engn & Environm Technol, E-47011 Valladolid, Spain
[3] Delft Univ Technol, Lab Biocatalysis & Organ Chem, Fac Sci Appl, Dept Biotechnol, NL-2628 BL Delft, Netherlands
[4] Fac Mech Maritime & Mat Engn, Dept Proc & Energy, Lab Proc Equipment, NL-2628 CA Delft, Netherlands
[5] Petr Inst, Dept Chem Engn, Abu Dhabi, U Arab Emirates
关键词
PHASE-BEHAVIOR; SOLUTES; WATER; CHROMATOGRAPHY; ACID;
D O I
10.1021/je100998r
中图分类号
O414.1 [热力学];
学科分类号
摘要
The paper reports infinite dilution activity coefficients of a series of polar and nonpolar solutes (alkanes, alcohols, ketones, ethers, aromatic hydrocarbons, halogenated compounds) in 1-butyl-3-methylimidazolium nitrate and 1,1-hydroxypropyl-3-methylimidazolium nitrate ionic liquids at (323, 333, and 343) K. The data were measured by gas-liquid chromatography using the ionic liquid as a stationary phase.
引用
收藏
页码:517 / 520
页数:4
相关论文
共 22 条
  • [1] High-pressure phase behavior of carbon dioxide with imidazolium-based ionic liquids
    Aki, SNVK
    Mellein, BR
    Saurer, EM
    Brennecke, JF
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (52) : 20355 - 20365
  • [2] Application of a group contribution equation of state for the thermodynamic modeling of the binary systems CO2-1-butyl-3-methyl imidazolium nitrate and CO2-1-hydroxy-1-propyl-3-methyl imidazolium nitrate
    Bermejo, M. D.
    Martin, A.
    Foco, G.
    Cocero, M. J.
    Bottini, S. B.
    Peters, C. J.
    [J]. JOURNAL OF SUPERCRITICAL FLUIDS, 2009, 50 (02) : 112 - 117
  • [3] Liquid-Vapor Equilibrium of the Systems Butylmethylimidazolium Nitrate-CO2 and Hydroxypropylmethylimidazolium Nitrate-CO2 at High Pressure: Influence of Water on the Phase Behavior
    Bermejo, M. Dolores
    Montero, Marta
    Saez, Elisa
    Florusse, Louw J.
    Kotlewska, Aleksandra J.
    Cocero, M. Jose
    van Rantwijk, Fred
    Peters, Cor J.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (43) : 13532 - 13541
  • [4] Influence of the enzyme concentration on the phase behaviour for developing a homogeneous enzymatic reaction in ionic liquid-CO2 media
    Bermejo, Maria Dolores
    Kotlewska, Aleksandra J.
    Florusse, Louw J.
    Cocero, Maria Jose
    van Rantwijk, Fred
    Peters, Cor J.
    [J]. GREEN CHEMISTRY, 2008, 10 (10) : 1049 - 1054
  • [5] Cammarata L, 2001, PHYS CHEM CHEM PHYS, V3, P5192, DOI 10.1039/b106900d
  • [6] Confined rapid thermolysis/FTIR/ToF studies of imidazolium-based ionic liquids
    Chowdhury, A
    Thynell, ST
    [J]. THERMOCHIMICA ACTA, 2006, 443 (02) : 159 - 172
  • [7] Conder J.R., 1979, PHYSICOCHEMICAL MEAS
  • [8] DIN C, 1995, LAT AM APPL RES, V25, P243
  • [9] Infinite dilution activity coefficients in mono-, di-, and tripalmitin and palmitic acid
    Foco, G
    Bermudez, R
    Bottini, S
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (05) : 1071 - 1074
  • [10] Activity coefficients at infinite dilution in 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquids
    Foco, Gloria M.
    Bottini, Susana B.
    Quezada, Nathalie
    de la Fuente, Juan C.
    Peters, Cor J.
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (03) : 1088 - 1091