Photocatalytic Synthesis of Sulfinamides and Sulfoxides from Nitroarenes and Thiophenols

被引：17

作者：

Feng, Chuan-Wei ^{[1
]}

Wang, Dan-Yan ^{[1
]}

Lu, Hui-Ling ^{[1
]}

Xi, Zi-Wei ^{[1
,2
]}

Shen, Yong-Miao ^{[1
,3
]}

Cao, Jianyu ^{[4
]}

机构：

[1] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China

[2] Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

[3] Zhejiang Univ, Key Lab Excited State Mat Zhejiang Prov, Hangzhou 310027, Peoples R China

[4] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China

来源：

ORGANIC LETTERS | 2022年 / 24卷 / 24期

关键词：

ASYMMETRIC-SYNTHESIS; THIOLS; ARYL; REDUCTION; SULFINYLATION; ACIDS;

D O I：

10.1021/acs.orglett.2c01824

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We present an efficient and versatile visible light-driven methodology for synthesizing sulfinamides and sulfoxides using nitroarenes as the nitrogen source and thiophenols as the sulfur source. The switch-over of the two reaction pathways was achieved by changing the type of photocatalyst and the amount of thiophenol in the reaction mixture. The reaction proceeds under mild conditions with good functional group tolerance and can easily be scaled up.

引用

页码：4485 / 4489

页数：5

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