Carbonyl(eta(4)-1,3-cyclohexadiene)[(eta(5),kappa N)-2-methylaminoethylcyclopentadienyl]molybdenum(II) hexafluorophosphate

被引：0

作者：

Wang, TF

Wen, YS

机构：

[1] Institute of Chemistry, Academia Sinica, Taipei

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195010328

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pseudotetrahedral structure of [Mo(C8H12N)(C6H8)(CO)]PF6 has a transoid CH3-N-Mo-CO arrangement. The amino group coordinates to the Mo atom intramolecularly, causing the side chain to bend away from the cyclopentadienyl plane by about 9.3 degrees.

引用

页码：525 / 526

页数：2

共 5 条

[1]

GABE EJ, 1987, ACTA CRYSTALLOGR A, V43, pC294

[2]

Johnson C. K., 1976, ORNL5138

[3] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].