Reversible guest-induced magnetic and structural single-crystal-to-single-crystal transformation in microporous coordination network {[Ni(cyclam)]3[W(CN)8]2}n

被引：75

作者：

Nowicka, Beata

Rams, Michal

Stadnicka, Katarzyna

Sieklucka, Barbara

机构：

[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

[2] Jagiellonian Univ, M Smoluchowski Inst Phys, PL-30059 Krakow, Poland

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 20期

关键词：

D O I：

10.1021/ic701168x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Planar honeycomb-like coordination network {[Ni(cyclam)](3)[W(CN)(8)](2)}(n) (cyclam = 1,4,8,11-tetraazacyclotetradecane) was obtained in the self-assembly reaction of [Ni(cyclam)](2+) and [W(CN)](8)(3-). Its structure is characterized by void channels along the a axis. The compound shows reversible water adsorption in the temperature range of 25-40 degrees C with the formation of {[Ni-(cyclam)](3)[W(CN)(8)](2)}n center dot 16nH(2)O, accompanied by single-crystal-to-single-crystal transformation. The structural transformation significantly changes the character of intraplane magnetic exchange interactions.

引用

页码：8123 / 8125

页数：3

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