Reversible guest-induced magnetic and structural single-crystal-to-single-crystal transformation in microporous coordination network {[Ni(cyclam)]3[W(CN)8]2}n

被引：75
|
作者：
Nowicka, Beata
Rams, Michal
Stadnicka, Katarzyna
Sieklucka, Barbara
机构：
[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland
[2] Jagiellonian Univ, M Smoluchowski Inst Phys, PL-30059 Krakow, Poland
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 20期
关键词：
D O I：
10.1021/ic701168x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Planar honeycomb-like coordination network {[Ni(cyclam)](3)[W(CN)(8)](2)}(n) (cyclam = 1,4,8,11-tetraazacyclotetradecane) was obtained in the self-assembly reaction of [Ni(cyclam)](2+) and [W(CN)](8)(3-). Its structure is characterized by void channels along the a axis. The compound shows reversible water adsorption in the temperature range of 25-40 degrees C with the formation of {[Ni-(cyclam)](3)[W(CN)(8)](2)}n center dot 16nH(2)O, accompanied by single-crystal-to-single-crystal transformation. The structural transformation significantly changes the character of intraplane magnetic exchange interactions.
引用
收藏
页码：8123 / 8125
页数：3
相关论文
共 50 条
  • [21] Single-crystal-to-single-crystal transformation of a coordination polymer from 2D to 3D by [2+2] photodimerization assisted by a coexisting flexible ligand
    Lee, Jae Hwa
    Park, Sungbin
    Jeoung, Sungeun
    Moon, Hoi Ri
    CRYSTENGCOMM, 2017, 19 (27): : 3719 - 3722
  • [22] Tuning the dynamic magnetic behaviour and proton conductivity via water-induced reversible single-crystal to single-crystal structural transformation
    Ji, Xiao-Qin
    Sun, Rong
    Xiong, Jin
    Sun, Hao-Ling
    Gao, Song
    JOURNAL OF MATERIALS CHEMISTRY C, 2021, 9 (44) : 15858 - 15867
  • [23] R-Substituent-Induced Structural Diversity and Single-Crystal to Single-Crystal Transformation of Coordination Polymers: Synthesis, Luminescence, and Magnetic Behaviors
    Zhang, Zhen
    Zhou, Jie
    Sun, Han Xu
    He, Mei
    Li, Wei
    Du, Lin
    Xie, Mingjin
    Zhao, Qi-Hua
    CRYSTAL GROWTH & DESIGN, 2021, 21 (09) : 5086 - 5099
  • [24] Reversible switching of Cu-tetracarboxylic-based coordination polymers through in situ single-crystal-to-single-crystal structural transformation and their impact on carbon-based composite derivatives, fluorescence, and adsorption properties
    Liu, Yu
    Wang, Yan
    Li, Wen-Ze
    Yang, Ai-Ai
    Zhang, Xiao-Sa
    Liu, Hong-Zhu
    Wang, Zhong-Gang
    JOURNAL OF SOLID STATE CHEMISTRY, 2021, 304
  • [25] Exploration of Solid-State [2+2] Photodimerization in the Coordination Polymers of Rigid and Linear Diene: Single-Crystal-to-Single-Crystal Transformation of a 2D Coordination Polymer to a 3D Coordination Polymer
    Sultana, Shaheen
    Mandal, Rajorshi
    Biradha, Kumar
    CRYSTAL GROWTH & DESIGN, 2024, 24 (12) : 5365 - 5373
  • [26] Spin switching in tris(8-aminoquinoline)iron(II) (BPh4)2: quantitative guest-losing dependent spin crossover properties and single-crystal-to-single-crystal transformation
    Yang, Feng-Lei
    Chen, Xin
    Wu, Wen-Hao
    Zhang, Jing-Hang
    Zhao, Xiang-Mei
    Shi, Yan-Hui
    Shen, Fei
    DALTON TRANSACTIONS, 2019, 48 (01) : 231 - 241
  • [27] A rare thermally induced single crystal to single crystal transformation from a 2D chiral coordination polymer to a 3D chiral coordination polymer
    Zhu, Ping
    Gu, Wen
    Zhang, Li-Zhi
    Liu, Xin
    Tian, Jin-Lei
    Yan, Shi-Ping
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 19 (19) : 2971 - 2974
  • [28] Anion-Controlled Synthesis of Enantiomeric Twofold Interpenetrated 3D Zinc(II) Coordination Polymer with Ligand Substitution-Induced Single-Crystal-to-Single-Crystal Transformation and Photocatalysis
    Kaeosamut, Nippich
    Chimupala, Yothin
    Yimklan, Saranphong
    CRYSTAL GROWTH & DESIGN, 2021, 21 (05) : 2942 - 2953
  • [29] Magnetic and structural studies of a Tb2Ni3Si5 single crystal
    Hashimoto, Y
    Kajio, T
    Kawano, S
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1999, 60 (8-9) : 1221 - 1224
  • [30] A 3D MOF showing unprecedented solvent-induced single-crystal-to-single-crystal transformation and excellent CO2 adsorption selectivity at room temperature
    Qin, Tao
    Gong, Jun
    Ma, Junhan
    Wang, Xin
    Wang, Yonghua
    Xu, Yan
    Shen, Xuan
    Zhu, Dunru
    CHEMICAL COMMUNICATIONS, 2014, 50 (100) : 15886 - 15889
12345