A simple thermodynamic description of the combined Einstein and elastic models

被引:12
作者
Balcerzak, Tadeusz [1 ]
Szalowski, Karol [1 ]
Jascur, Michal [2 ]
机构
[1] Univ Lodz, Dept Solid State Phys, PL-90236 Lodz, Poland
[2] Safarik Univ, Dept Theoret Phys & Astrophys, Fac Sci, Kosice 04154, Slovakia
关键词
EQUATION-OF-STATE; FINITE STRAIN; EXPERIMENTAL COMPRESSIONS; UNIVERSAL EQUATION; THERMAL-EXPANSION; HIGH-PRESSURES; WIDE RANGES; SOLID ARGON; TEMPERATURE; CONSTANTS;
D O I
10.1088/0953-8984/22/42/425401
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
A simple application of the Einstein model combined with an elastic description of the solid state is developed. The frequency of quantum oscillators has been assumed as volume dependent and elastic energy terms with a static character have been included to complete the description. Such an extension enables us to construct the complete thermodynamics. In particular, the model yields a practical equation of state and describes the thermal expansion coefficient as well as the isothermal compressibility of solids. The thermodynamic properties resulting from the Gibbs free-energy analysis have been calculated and are illustrated in figures. Some comparisons of the theoretical results with experimental data for solid argon have been made.
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页数:11
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