The relations between the microstructure and the capacity decay rate of MLNi3.8Co0.6Mn0.55Ti0.05 alloy.: I.: Capacity decay rate measurements

被引:12
作者
Li, CJ [1 ]
Wang, XL [1 ]
机构
[1] MMI, Cent Iron & Steel Res Inst, Adv Mat Inst, Beijing 100081, Peoples R China
关键词
capacity decay rate; heat treatment; hydrogen-storage alloy; metal hydrogen electrode;
D O I
10.1016/S0925-8388(98)00489-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The capacity decay rates of MLNi3.8Co0.6Mn0.55Ti0.05 alloys prepared using different methods were investigated by electrochemical charge-discharge cycling tests. The cycle stability of the alloy could be improved by rapid solidification of the melted alloy compared with the corresponding as-cast alloy of the same composition. The capacity decay rate could be further decreased by annealing at a lower temperature such as 673 K. However, the capacity decay rate increased to a much higher level when the quenched alloy was annealed at a higher temperature such as 1073 K. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:242 / 245
页数:4
相关论文
共 17 条
[1]   THE EFFECT OF HYDROGEN ABSORPTION ON THE ELECTRICAL RESISTIVITIES OF LANI5 AND MMNI4.5MN0.5 FILMS (MM = MISCH METAL) [J].
ADACHI, G ;
NIKI, K ;
NAGAI, H ;
SHIOKAWA, J .
JOURNAL OF THE LESS-COMMON METALS, 1982, 88 (01) :213-216
[2]   THE EFFECT OF HYDROGEN ABSORPTION ON THE ELECTRICAL-RESISTIVITY OF LANI5 FILM [J].
ADACHI, GY ;
NIKI, KI ;
SHIOKAWA, J .
JOURNAL OF THE LESS-COMMON METALS, 1981, 81 (02) :345-348
[3]  
LI C, IN PRESS J POWER SOU
[4]   Effect of annealing on the hydrogen-storage properties of rapidly quenched AB5-type alloys [J].
Li, CH ;
Wang, XL ;
Wu, JM ;
Wang, CY .
JOURNAL OF POWER SOURCES, 1998, 70 (01) :106-109
[5]   Investigations on ML(NiCoMnTi)5 alloys prepared with different solidification rates [J].
Li, CJ ;
Wang, XL ;
Wang, CY .
JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 266 (1-2) :300-306
[6]  
LI CJ, IN PRESS ELECTROCHEM
[7]   AMORPHOUS LA-NI THIN-FILM ELECTRODES [J].
LI, Y ;
CHENG, YT .
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 223 (01) :6-12
[8]  
MELI F, 1993, THESIS U FREIBURG
[9]   HYDROGEN STORAGE ALLOYS RAPIDLY SOLIDIFIED BY THE MELT-SPINNING METHOD AND THEIR CHARACTERISTICS AS METAL HYDRIDE ELECTRODES [J].
MISHIMA, R ;
MIYAMURA, H ;
SAKAI, T ;
KURIYAMA, N ;
ISHIKAWA, H ;
UEHARA, I .
JOURNAL OF ALLOYS AND COMPOUNDS, 1993, 192 (1-2) :176-178
[10]   IN-SITU X-RAY-DIFFRACTION - A USEFUL TOOL TO INVESTIGATE HYDRIDE FORMATION REACTIONS [J].
NOTTEN, PHL ;
DAAMS, JLC ;
DEVEIRMAN, AEM ;
STAALS, AA .
JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 209 :85-91