Hydrazinoazadipeptides as aromatic solvent gelators

被引：29

作者：

Carré, A ^{[1
]}

Le Grel, P ^{[1
]}

Baudy-Floc'h, M ^{[1
]}

机构：

[1] Univ Rennes 1, UMR CNRS 6510, Lab Synth & Electrosynth Organ, F-35042 Rennes, France

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 10期

关键词：

hydrazinoazapeptides; gel; electron microscopy; hydrogen bond;

D O I：

10.1016/S0040-4039(01)00035-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of a small amount of HCl, hydrazinoazadipeptides form thermoreversible physical gels with aromatic solvents. These gels are stable to 70-90 degreesC, and can be stored for months. Electron microscopy reveals that in these solvents. pseudopeptides self-assemble into elongated and very thin fibers, which in turn form a three-dimensional network that traps solvent molecules. Infrared studies showed that aggregation is accompanied by the formation of a hydrogen-bonded network between NH and CO of the hydrazinopeptides. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1887 / 1889

页数：3

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