Improvement in stannate chemical conversion coatings on AZ91 D magnesium alloy using the potentiostatic technique

被引:106
作者
Elsentriecy, Hassan H. [1 ]
Azumi, Kazuhisa [1 ]
Konno, Hidetaka [1 ]
机构
[1] Hokkaido Univ, Grad Sch Engn, Sapporo, Hokkaido 0608628, Japan
关键词
AZ91; D; stannate; conversion coatings; corrosion resistance; potentiostatic technique;
D O I
10.1016/j.electacta.2007.08.015
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The deposition of stannate chemical conversion coatings on AZ91 D magnesium alloy by using the potentiostatic technique was investigated to improve uniformity and corrosion protection performance of the coating film. It was found that anodic polarization during the stannate conversion process accelerated dissolution of magnesium ions and promoted deposition of the coating film. Optimal polarization potential was explored as a function of corrosion protection performance evaluated by potentiodynamic polarization curves in borate buffer solution. Scanning electron microscope observation and electrochemical corrosion tests of the stannate-coated samples confirmed significant improvement in uniformity and corrosion resistance of coatings deposited by the potentiostatic technique compared to those of coatings deposited by the simple immersion method. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1006 / 1012
页数:7
相关论文
共 7 条
[1]   About some corrosion mechanisms of AZ91D magnesium alloy [J].
Ballerini, G ;
Bardi, U ;
Bignucolo, R ;
Ceraolo, G .
CORROSION SCIENCE, 2005, 47 (09) :2173-2184
[2]   Kinetics of the development of a nonchromate conversion coating for magnesium alloys and magnesium-based metal matrix composites [J].
González-Nuñez, MA ;
Skeldon, P ;
Thompson, GE ;
Karimzadeh, H .
CORROSION, 1999, 55 (12) :1136-1143
[3]   A NON-CHROMATE CONVERSION COATING FOR MAGNESIUM ALLOYS AND MAGNESIUM-BASED METAL-MATRIX COMPOSITES [J].
GONZALEZNUNEZ, MA ;
NUNEZLOPEZ, CA ;
SKELDON, P ;
THOMPSON, GE ;
KARIMZADEH, H ;
LYON, P ;
WILKS, TE .
CORROSION SCIENCE, 1995, 37 (11) :1763-1772
[4]   Protective coatings on magnesium and its alloys - a critical review [J].
Gray, JE ;
Luan, B .
JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 336 (1-2) :88-113
[5]   Sol-gel coatings with phosphonate functionalities for surface modification of magnesium alloys [J].
Khramov, A. N. ;
Balbyshev, V. N. ;
Kasten, L. S. ;
Mantz, R. A. .
THIN SOLID FILMS, 2006, 514 (1-2) :174-181
[6]   Formation and properties of stannate conversion coatings on AZ61 magnesium alloys [J].
Lin, CS ;
Lin, HC ;
Lin, KM ;
Lai, WC .
CORROSION SCIENCE, 2006, 48 (01) :93-109
[7]   The corrosion protection afforded by rare earth conversion coatings applied to magnesium [J].
Rudd, AL ;
Breslin, CB ;
Mansfeld, F .
CORROSION SCIENCE, 2000, 42 (02) :275-288